Facile Encapsulation of Ln(II) Ions into Cryptate Complexes from LnI2 (THF)2 Precursors (Ln = Sm, Eu, Yb)

被引：18

作者：

Huh, Daniel N. ^{[1
]}

Ziller, Joseph W. ^{[1
]}

Evans, William J. ^{[1
]}

机构：

[1] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA

来源：

INORGANIC CHEMISTRY | 2019年 / 58卷 / 15期

基金：

美国国家科学基金会;

关键词：

DIVALENT LANTHANIDE; COORDINATION CHEMISTRY; MOLECULAR-STRUCTURE; RARE-EARTH; EUROPIUM(II); CRYSTAL;

D O I：

10.1021/acs.inorgchem.9b01049

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reactivity of LnI(2) (THF)(2) (Ln = Sm, Eu, Yb; THF = tetrahydrofuran) with 2.2.2-cryptand (crypt) was explored to see if these readily accessible precursors could provide new examples of lanthanide-in-crypt complexes. The crystallographically characterized Ln(II)-in-crypt complexes [Ln(crypt)(DMF)(2)][I](2) (Ln = Sm, Eu) and [Yb(crypt)(DMF)]-[I](2) (DMF = dimethylformamide) were synthesized by reacting LnI(2) (THF)(2) (Ln = Sm, Eu, Yb) with crypt in THF and recrystallizing from DMF. Crystallographic data were also obtained on the Ln(II)-in-crypt (Ln = Sm, Eu) complexes [Ln(crypt)(DMF)(2)][BPh4](2), which were synthesized by addition of 2 equiv of NaBPh4 to [Ln(crypt)(DMF)(2)][I](2).

引用

收藏

页码：9613 / 9617

页数：5

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