Etherification of aliphatic polyhydric alcohols with allyl chloride

被引：0

作者：

Spadlo, Marian ^{[1
]}

Dziwinski, Euzebiusz ^{[1
]}

机构：

[1] Inst Ciezkiej Syntezy Org Blachownia, PL-47225 Kedzierzyn Kozle, Poland

来源：

PRZEMYSL CHEMICZNY | 2006年 / 85卷 / 07期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Allyl chloride was used to etherily (1) glycerol, (H) trimethylolpropane or (ill) pentaerythritol in aq. 47% NaOH over an ammonium salt (Bu4NI, Bu4NHSO4) as a phase transfer catalyst. In 4-6 hours at 60-70 degrees C, (i) and (iii) gave 51-60% of ether products, selectivity 91%, with (i) tri (40%) and (iii) tri (31%) and tetraallyl ether (28016) as the major products. In 3 hours at 90 degrees C, (ii) gave 99% of ether products with the diallyl deriv. (75%) as the major product Diallyl ether was the by-product prepd. from diallyl alc. that formed reaction conditions.

引用

页码：483 / 486

页数：4

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