Palladium Complex Immobilized on Graphene Oxide as an Efficient and Recyclable Catalyst for Suzuki Coupling Reaction

被引：72

作者：

Bai, Chan ^{[1
]}

Zhao, Qingshan ^{[1
]}

Li, Yang ^{[1
]}

Zhang, Guoliang ^{[1
]}

Zhang, Fengbao ^{[1
]}

Fan, Xiaobin ^{[1
]}

机构：

[1] Tianjin Univ, State Key Lab Chem Engn, Sch Chem Engn & Technol, Collaborat Innovat Ctr Chem Sci & Engn, Tianjin 300072, Peoples R China

来源：

CATALYSIS LETTERS | 2014年 / 144卷 / 09期

基金：

中国国家自然科学基金;

关键词：

Graphene oxide; Heterogeneous catalysis; Suzuki reaction; Immobilization; Palladium; ASYMMETRIC HYDROGENATION; MIYAURA REACTION; NANOPARTICLES; REDUCTION; SUPPORT; HETEROCYCLES; OXIDATION; SHEETS; FILMS;

D O I：

10.1007/s10562-014-1299-0

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A graphene supported palladium (Pd) catalyst for Suzuki coupling reaction has been successfully prepared by immobilizing Pd(II) onto graphene oxide surface through the in situ coordination interaction with aminosilane ligand spacers. This catalyst showed high catalytic activities in the Suzuki coupling of various aryl halides and phenylboronic acid. Moreover, it could be readily recycled and reused for several times without discernible loss of its catalytic activity.

引用

页码：1617 / 1623

页数：7

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