N2•3-: Filling a Gap in the N2n- Series

被引：18

作者：

Kaim, Wolfgang ^{[1
]}

Sarkar, Biprajit ^{[1
]}

机构：

[1] Univ Stuttgart, Inst Anorgan Chem, D-70550 Stuttgart, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 50期

关键词：

coordination chemistry; nitrogen; radical complexes; rare-earth metals; superoxide analogues; BIOLOGICAL NITROGEN-FIXATION; COORDINATION CHEMISTRY; METAL-COMPLEXES; ANION-RADICALS; DINITROGEN; ACTIVATION; ELECTRON; LIGANDS; REDUCTION; SPECTROELECTROCHEMISTRY;

D O I：

10.1002/anie.200904968

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[Chemical Equation Presented] The unexpected stability of the exotic N 2.3- species has been observed in its complexes with Dy3+ and Y3+. The three-electron reduction Product of N2is iso-electronic with superoxide O2.- (see scheme) and is a possible bound intermediate in the conversion of N2 into NH3. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：9409 / 9411

页数：3

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