Employing tetrahedral {Zn4O} clusters as building subunits to construct a new acentric metal-organic framework

被引：8
作者：
Bu, Xianzhong [1 ]
Wei, Zongwu [2 ]
Zhang, Chonghui [1 ]
Ren, Shaofeng [3 ]
机构：
[1] Xian Univ Architecture & Technol, Coll Mat & Mineral Resources, Xian 710055, Peoples R China
[2] Guangxi Univ, Coll Resources & Met, Nanning 530004, Peoples R China
[3] Southwest Energy & Mineral Resources Corp Co Ltd, Guiyang 550004, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2014年 / 48卷
关键词：
Zn(II) compound; Hydrothermal synthesis; Tetrahedral cluster; Luminescence; ZINC COORDINATION POLYMERS; TUNABLE PHOTOLUMINESCENCE; ACTIVE PROPERTIES; LUMINESCENCE; LIGAND;
D O I：
10.1016/j.inoche.2014.08.017
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Hydrothermal reaction of H3L and Zn(NO3)(2) produced a new noncentrosymmetric Zn(II) compound, namely [Zn-4(mu(4)-O)(L)(2)(H2O)(3)](n) (1 H3L = biphenyl-3,4,5-tricarboxylic acid). Single-crystal X-ray diffraction analysis reveals that compound 1 crystallizes in the acentric Pna2(1) space group and features a 3D framework based on isolated tetrahedral {Zn4O} clusters as building subunits. Topological analysis reveals that it can be simplified into a 3-nodal (3,3,6)-connected topological network with the Schlafli symbol of (4.6(2)}2(4(2).6(7).8(6)} In addition, the nonlinear optic and luminescent properties of this compound were also investigated at room temperature. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：158 / 160
页数：3
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