Rational Construction of 2D and 3D Borromean Arrayed Organic Crystals by Hydrogen-Bond-Directed Self-Assembly

被引:69
作者
Men, Yong-Biao [1 ]
Sun, Junliang [2 ]
Huang, Zhi-Tang [1 ]
Zheng, Qi-Yu [1 ]
机构
[1] Chinese Acad Sci, Inst Chem, CAS Key Lab Mol Recognit & Funct, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
[2] Stockholm Univ, Struct Chem & Berzelii Ctr EXSELENTon Porous, S-10691 Stockholm, Sweden
基金
中国国家自然科学基金;
关键词
Borromean rings; crystal engineering; hydrogen bonds; self-assembly; topology; SHOWING STRUCTURAL DIVERSITY; TRIMESIC ACID; COORDINATION POLYMERS; NETWORKS; POLYMORPHISM; TOPOLOGY; COMPLEX; DESIGN;
D O I
10.1002/anie.200806198
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Borromean organic networks: The rigid and trigonal pyramidal molecule, 1,3,5-tris(4-carboxyphenyl) adamantane (TCA), self-assembles into a 2D Borromean linked network by hydrogen bonds. Different linkers (methanol, phenazine, 4,4′ -bipyridine, and 4,4′ - azopyridine) result in more complex Borromean networks or a 3D polycatenation network. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:2873 / 2876
页数:4
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