High-pressure optical studies on R-line fluorescence lifetime in Al2O3:V2+

被引:0
作者
Jovanic, Branislav R. [1 ]
Radenkovic, Bozidar [2 ]
Despotovic-Zrakic, Marijana [2 ]
Bogdanovic, Zorica [2 ]
Barac, Dusan [2 ]
机构
[1] Univ Belgrade, Inst Phys, Lab Multidisciplinary Res, Zemun, Serbia
[2] Univ Belgrade, Fac Org Sci, Lab Simulat, Belgrade, Serbia
来源
RADIATION EFFECTS AND DEFECTS IN SOLIDS | 2018年 / 173卷 / 3-4期
关键词
Al2O3:V2+; high pressure; lifetime; fluorescence; optical properties; THEORETICAL CALCULATIONS; INDUCED SHIFTS; ELECTRONIC POLARIZABILITIES; IONS; RUBY; TEMPERATURE; SPECTRUM; STATE; FIELD; TRANSITIONS;
D O I
10.1080/10420150.2018.1428976
中图分类号
TL [原子能技术]; O571 [原子核物理学];
学科分类号
0827 ; 082701 ;
摘要
The effect of high hydrostatic pressure (up to 10.3GPa) at room temperature on fluorescence lifetime for R line ((2)E(4)A(2) transition) in ruby Al2O3:V2+ was studied. The performed studies show the linear increase of with increasing pressure. At 10.3GPa, is about 1.36 times higher than at ambient pressure. The obtained trend was explained by a model which considered the effect of pressure on through an induced change of line position, inter-ionic distance, compressibility, and molecular polarizability. A good agreement between the calculated and experimental values for was obtained.
引用
收藏
页码:261 / 268
页数:8
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