Low-Temperature and Hysteresis-Free Electron-Transporting Layers for Efficient, Regular, and Planar Structure Perovskite Solar Cells

被引:70
作者
Hou, Yi [1 ,2 ]
Quiroz, Cesar Omar Ramirez [1 ]
Scheiner, Simon [3 ]
Chen, Wei [1 ,2 ]
Stubhan, Tobias [1 ]
Hirsch, Andreas [4 ]
Halik, Marcus [3 ]
Brabec, Christoph J. [1 ,5 ]
机构
[1] Univ Erlangen Nurnberg, Inst Mat Elect & Energy Technol I MEET, Dept Mat Sci & Engn, D-91058 Erlangen, Germany
[2] Erlangen Grad Sch Adv Optic Technol SAOT, D-91052 Erlangen, Germany
[3] Univ Erlangen Nurnberg, Inst Polymer Mat, Organ Mat & Devices, D-91058 Erlangen, Germany
[4] Univ Erlangen Nurnberg, Dept Chem & Pharm, D-91054 Erlangen, Germany
[5] Bavarian Ctr Appl Energy Res ZAE Bayern, D-91058 Erlangen, Germany
关键词
perovskite solar cells; low-temperature solution processed; electron-transporting layers; hysteresis-free solar cells; SELF-ASSEMBLED MONOLAYERS; CH3NH3PBI3; PHOTOVOLTAICS; PERFORMANCE; OXIDE; ORIGIN;
D O I
10.1002/aenm.201501056
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
With the aim of fully utilizing the low processing temperatures of perovskite solar cells, significant progress in replacing high temperature processed TiO2 by various low-temperature solution processed electron transporting layers (LT-ETLs) was recently reported. Here, recent progress in the development of LT-ETLs for regular planar structure perovskite solar cells, which is essential for achieving high efficiency in parallel to avoiding hysteresis, is reviewed. In addition, the application of a novel hysteresis-free LT-ETLs for regular planar perovskite solar cells in our laboratory is briefly discussed. By incorporating a low temperature processed WOx nanoparticular layer in combination with a mixed fullerene functionalized self-assembled monolayers (SAMs), a regular, planar structure, and hysteresis-free perovskite solar cell with a maximum efficiency of almost 15% can be fabricated.
引用
收藏
页数:7
相关论文
共 52 条
[1]   A Universal Interface Layer Based on an Amine-Functionalized Fullerene Derivative with Dual Functionality for Efficient Solution Processed Organic and Perovskite Solar Cells [J].
Azimi, Hamed ;
Ameri, Tayebeh ;
Zhang, Hong ;
Hou, Yi ;
Quiroz, Cesar Omar Ramirez ;
Min, Jie ;
Hu, Mengyao ;
Zhang, Zhi-Guo ;
Przybilla, Thomas ;
Matt, Gebhard J. ;
Spiecker, Erdmann ;
Li, Yongfang ;
Brabec, Christoph J. .
ADVANCED ENERGY MATERIALS, 2015, 5 (08)
[2]   Towards low-cost, environmentally friendly printed chalcopyrite and kesterite solar cells [J].
Azimi, Hamed ;
Hou, Yi ;
Brabec, Christoph J. .
ENERGY & ENVIRONMENTAL SCIENCE, 2014, 7 (06) :1829-1849
[3]   Low-temperature processed meso-superstructured to thin-film perovskite solar cells [J].
Ball, James M. ;
Lee, Michael M. ;
Hey, Andrew ;
Snaith, Henry J. .
ENERGY & ENVIRONMENTAL SCIENCE, 2013, 6 (06) :1739-1743
[4]   Phosphonate- and Carboxylate-Based Self-Assembled Monolayers for Organic Devices: A Theoretical Study of Surface Binding on Aluminum Oxide with Experimental Support [J].
Bauer, Thilo ;
Schmaltz, Thomas ;
Lenz, Thomas ;
Halik, Marcus ;
Meyer, Bernd ;
Clark, Timothy .
ACS APPLIED MATERIALS & INTERFACES, 2013, 5 (13) :6073-6080
[5]   Using a two-step deposition technique to prepare perovskite (CH3NH3PbI3) for thin film solar cells based on ZrO2 and TiO2 mesostructures [J].
Bi, Dongqin ;
Moon, Soo-Jin ;
Haggman, Leif ;
Boschloo, Gerrit ;
Yang, Lei ;
Johansson, Erik M. J. ;
Nazeeruddin, Mohammad K. ;
Graetzel, Michael ;
Hagfeldt, Anders .
RSC ADVANCES, 2013, 3 (41) :18762-18766
[6]  
Brabec CJ, 2001, ADV FUNCT MATER, V11, P15, DOI 10.1002/1616-3028(200102)11:1<15::AID-ADFM15>3.0.CO
[7]  
2-A
[8]  
Cells S. S., 2014, ACS NANO, V8, P362
[9]   Analysis of Electron Transfer Properties of ZnO and TiO2 Photoanodes for Dye-Sensitized Solar Cells [J].
Chandiran, Aravind Kumar ;
Abdi-Jalebi, Mojtaba ;
Nazeeruddin, Mohammad K. ;
Graetzel, Michael .
ACS NANO, 2014, 8 (03) :2261-2268
[10]   Emergence of Hysteresis and Transient Ferroelectric Response in Organo-Lead Halide Perovskite Solar Cells [J].
Chen, Hsin-Wei ;
Sakai, Nobuya ;
Ikegami, Masashi ;
Miyasaka, Tsutomu .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2015, 6 (01) :164-169