Bent versus linear imido ligands in five-co-ordinate molybdenum complexes

被引：45

作者：

Gibson, VC ^{[1
]}

Marshall, EL ^{[1
]}

Redshaw, C ^{[1
]}

Clegg, W ^{[1
]}

Elsegood, MRJ ^{[1
]}

机构：

[1] UNIV NEWCASTLE UPON TYNE,DEPT CHEM,NEWCASTLE TYNE NE1 7RU,TYNE & WEAR,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1996年 / 22期

关键词：

D O I：

10.1039/dt9960004197

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A comparison of the molecular structures of the five-co-ordinate bis(imido) and imido alkylidene molybdenum complexes [Mo(NC6H3Pr2i-2,6)(L)(L')]; where L is a tridentate pyridinediolato ligand and L' is either NC6H3Pr2i-2,6 or CHCMe(2)Ph, strongly supports the notion that the nitrogen of the bent imido ligand in the bis(imido) complex is sp(2)-hybridised.

引用

页码：4197 / 4199

页数：3

共 13 条

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