Transfer of alk-1-enyl group from boron to aluminium: a novel way to prepare (E)-alk-1-enyldiisobutylalanes

被引：12

作者：

Hoshi, M ^{[1
]}

Shirakawa, K ^{[1
]}

机构：

[1] Kitami Inst Technol, Dept Appl & Environm Chem, Kitami, Hokkaido 0908507, Japan

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 18期

关键词：

D O I：

10.1039/b206541j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of (E)-alk-1-enyldicyclohexylboranes 1 with diisobutylaluminium hydride (DIBAL-H) in the presence of hex-1-ene at room temperature results in transfer of the alk-1-enyl group from boron to aluminium to give (E)-alk-1-enyldiisobutylalanes 2 with retention of configuration at the double bond.

引用

页码：2146 / 2147

页数：2

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