Study of the Properties of a Biodegradable Polymer Filled with Different Wood Flour Particles

被引:8
|
作者
Parres, Francisco [1 ]
Angel Peydro, Miguel [1 ]
Juarez, David [1 ]
Arrieta, Marina P. [2 ,3 ]
Aldas, Miguel [4 ]
机构
[1] Univ Politecn Valencia, Dept Ingn Mecan & Mat, Plz Ferrandiz y Carbonell S-N, Alcoy 03801, Spain
[2] Univ Politecn Madrid ETSII UPM, Dept Ingn Quim & Medio Ambiente, Escuela Politecn Super Ingenieros Ind, Calle Jose Gutierrez Abascal 2, Madrid 28006, Spain
[3] Grp Invest Polimeros Caracterizac & Aplicac POLCA, Madrid 28006, Spain
[4] Escuela Politec Nacl, Dept Ciencia Alimentos & Biotecnol, Fac Ingn Quim & Agroind, Quito 170517, Ecuador
关键词
biopolymer; Solanyl (R); wood flour; Lignocel (R); lignocellulosic particles; fuller method; mechanical properties; rheological characterization; CELLULOSE NANOCRYSTALS; LINSEED OIL; PLA; COMPOSITES;
D O I
10.3390/polym12122974
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Lignocellulosic wood flour particles with three different sizes were used to reinforce Solanyl (R) type bioplastic in three compositions (10, 20, and 30 wt.%) and further processed by melt-extrusion and injection molding to simulate industrial conditions. The wood flour particles were morphologically and granulometric analyzed to evaluate their use as reinforcing filler. The Fuller method on wood flour particles was successfully applied and the obtained results were subsequently corroborated by the mechanical characterization. The rheological studies allowed observing how the viscosity was affected by the addition of wood flour and to recover information about the processing conditions of the biocomposites. Results suggest that all particles can be employed in extrusion processes (shear rate less than 1000 s(-1)). However, under injection molding conditions, biocomposites with high percentages of wood flour or excessively large particles may cause an increase in defective injected-parts due to obstruction of the gate in the mold. From a processing point of view and based on the biocomposites performance, the best combination resulted in Solanyl (R) type biopolymer reinforced with wood flour particles loaded up to 20 wt.% of small and medium particles size. The obtained biocomposites are of interest for injected molding parts for several industrial applications.
引用
收藏
页码:1 / 24
页数:24
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