Reversible binding and reduction of dinitrogen by a uranium(III) pentalene complex

被引：162

作者：

Cloke, FGN ^{[1
]}

Hitchcock, PB ^{[1
]}

机构：

[1] Univ Sussex, Chem Lab, Sch Chem Phys & Environm Sci, Brighton BN1 9QJ, E Sussex, England

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 32期

关键词：

D O I：

10.1021/ja027000e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The U(III) mixed-sandwich compound [U(η-Cp*)(η-C8H4{SiiPr3-1,4}2)] 1 may be prepared by sequential reaction of UI3 with KCp* followed by K2[C8H4{SiiPr3-1,4}2], and has been crystallographically characterized. 1 reacts reversibly with dinitrogen to afford dimeric [{U(η-Cp*)(η-C8H4{SiiPr3-1,4}2)}2(μ-η2:η2-N2)] 2 , whose X-ray crystal structure reveals a sideways-bound, bridging diazenido (N22-) ligand. Copyright © 2002 American Chemical Society.

引用

页码：9352 / 9353

页数：2

共 12 条

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