Effect of the incorporation of organoclay and melamine cyanurate on the flame retardancy and mechanical property of polyurethane foam

被引:4
作者
Hac Thi Nhung [1 ,2 ]
Pham Duy Linh [1 ]
Nguyen Thi Hanh [1 ,2 ]
Nguyen Thanh Nhan [1 ]
Ho Thi Oanh [1 ,2 ]
Nguyen Duc Tuyen [1 ]
Nguyen Van Tuyen [1 ,2 ]
Hoang Mai Ha [1 ,2 ]
机构
[1] Vietnam Acad Sci & Technol VAST, Inst Chem, 18 Hoang Quoc Viet, Hanoi 100000, Vietnam
[2] Grad Univ Sci & Technol, Vietnam Acad Sci & Technol, 18 Hoang Quoc Viet, Hanoi, Vietnam
关键词
Organoclay; melamine cyanurate; polyurethane foam; flame retardancy; EXPANDABLE GRAPHITE; PHOSPHORUS; NANOCOMPOSITES; PERFORMANCE; BEHAVIOR;
D O I
10.1002/vjch.201900046
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The polyurethane composites were prepared by a one-pot free-rising method with Melamine cyanurate (MC) and Cloisite 20A additives. Flame-retardant and mechanical properties of the foams were investigated. The vertical burning test showed that PUF composite loading 15 wt% MC was reached V0 classification of V-rating. Limiting oxygen index (LOI) test revealed that the PU foam changed from an especially flammable material (LOI = 18.4 %) to a flame-resistant material (LOI = 24.1 %) upon adding 25 wt% MC. However, the presence of MC reduced the compressive strength of the foam. In this report, we demonstrated the incorporation of organoclay and MC into PUF could improve the flame retardancy and the compressive strength of polyurethane foam.
引用
收藏
页码:368 / 374
页数:7
相关论文
共 25 条
[1]   A Comparison of the Effect of Different Flame Retardants on the Compressive Strength and Fire Behaviour of Rigid Polyurethane Foams [J].
Barikani, M. ;
Askari, F. ;
Barmar, M. .
CELLULAR POLYMERS, 2010, 29 (06) :343-357
[2]   Dependence of flame-retardant properties on density of expandable graphite filled rigid polyurethane foam [J].
Bian, Xiang-Cheng ;
Tang, Jian-Hua ;
Li, Zhong-Ming ;
Lu, Zhong-Yuan ;
Lu, Ai .
JOURNAL OF APPLIED POLYMER SCIENCE, 2007, 104 (05) :3347-3355
[3]   Comparison of the thermal decomposition behavior of a non-fire retarded and a fire retarded flexible polyurethane foam with phosphorus and brominated additives [J].
Chao, CYH ;
Wang, JH .
JOURNAL OF FIRE SCIENCES, 2001, 19 (02) :137-156
[4]   Thermal stability and flame retardancy of polyurethanes [J].
Chattopadhyay, D. K. ;
Webster, Dean C. .
PROGRESS IN POLYMER SCIENCE, 2009, 34 (10) :1068-1133
[5]   Thermal and flame retardation properties of melamine phosphate-modified epoxy resins [J].
Chen, WY ;
Wang, YZ ;
Chang, FC .
JOURNAL OF POLYMER RESEARCH, 2004, 11 (02) :109-117
[6]   Thermal degradation of polyurethane and polyurethane/expandable graphite coatings [J].
Duquesne, S ;
Le Bras, M ;
Bourbigot, S ;
Delobel, R ;
Camino, G ;
Eling, B ;
Lindsay, C ;
Roels, T .
POLYMER DEGRADATION AND STABILITY, 2001, 74 (03) :493-499
[7]  
Hoang Thai, 2007, J SCI TECHNOL, V45, P67
[8]  
Hung Hoang Tuan, 2012, J SCI TECHNOL, V50, P397
[9]   Bio-based engineered nanocomposite foam with enhanced mechanical and thermal barrier properties [J].
Kadam, H. ;
Bandyopadhyay-Ghosh, S. ;
Malik, N. ;
Ghosh, S. B. .
JOURNAL OF APPLIED POLYMER SCIENCE, 2019, 136 (07)