Structural Features of Monomeric Octahedral d 2-Rhenium(V) Monooxo Complexes with Oxygen Atoms of D, N Bidentate Chelating Ligands (L n ). Part 1: [ReO(L n )(Lmono)3] Complexes Containing Five-Membered Chelate Rings ReNC2O

被引:7
作者
Sergienko, V. S. [1 ,2 ]
Churakov, A. V. [1 ]
机构
[1] Rusdsian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia
[2] All Russia Inst Sci & Tech Informat, Moscow 125190, Russia
关键词
RHENIUM(V) OXO COMPLEXES; X-RAY-STRUCTURE; OXORHENIUM(V) COMPLEXES; TRANS-POSITIONS; CATALYTIC APPLICATION; EPOXIDATION REACTIONS; 8-HYDROXYQUINOLINE DERIVATIVES; CRYSTAL-STRUCTURES; DFT CALCULATIONS; NEUTRAL LIGANDS;
D O I
10.1134/S0036023618050121
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Structural features of 31 mononuclear octahedral d (2)-Re(V) monooxo complexes with singly charged oxygen atoms of bidentate chelating (D, N) ligands (L (n) ) [ReO(L (n) )(L-mono)(3)] (n = 1-19; L-mono is a monodentate ligand) have been considered. The O(L (n) ) atoms are trans to the D(oxo) ligands.
引用
收藏
页码:631 / 641
页数:11
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