Debye temperature of nanocrystalline Fe-Cr alloys obtained by mechanical alloying

被引:6
作者
Dubiel, S. M. [1 ]
Costa, B. F. O. [2 ]
Cieslak, J. [1 ]
Batista, A. C. [2 ]
机构
[1] AGH Univ Sci & Technol, Fac Phys & Appl Comp Sci, PL-30059 Krakow, Poland
[2] Univ Coimbra, Dept Phys, CFisUC, P-3004516 Coimbra, Portugal
关键词
Fe-Cr alloys; Mechanical alloying; Debye temperature; Mossbauer spectroscopy; X-ray diffraction; SIGMA-PHASE; MOSSBAUER SPECTROMETRY; TRANSFORMATIONS;
D O I
10.1016/j.jallcom.2015.07.067
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A series on nanocrystalline Fe100-xCrx alloys prepared by mechanical alloying was investigated with Xray diffraction (XRD), scanning electron microscopy (SEM) and Mossbauer spectroscopy (MS) techniques. XRD was used to structurally characterize the samples whereas MS permitted phase analysis as well as determination of the Debye temperature, theta(D). Concerning the latter, an enhancement relative to bulk theta(D)-values was revealed in the range of similar to 40 <= x <= similar to 50. In a sample of Fe55.5Cr44.5 two phases were detected viz. (1) crystalline and magnetic with theta(D) = 572 (56) K and (2) amorphous and paramagnetic with theta(D) = 405 (26) K. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:1246 / 1252
页数:7
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