Using DNA to Design Plasmonic Metamaterials with Tunable Optical Properties

被引:169
作者
Young, Kaylie L. [1 ,2 ]
Ross, Michael B. [1 ,2 ]
Blaber, Martin G. [1 ,2 ]
Rycenga, Matthew [1 ,2 ]
Jones, Matthew R. [3 ]
Zhang, Chuan [1 ,2 ]
Senesi, Andrew J. [1 ,2 ]
Lee, Byeongdu [4 ]
Schatz, George C. [1 ,2 ]
Mirkin, Chad A. [1 ,2 ,3 ]
机构
[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
[2] Northwestern Univ, Int Inst Nanotechnol, Evanston, IL 60208 USA
[3] Northwestern Univ, Dept Mat Sci & Engn, Evanston, IL 60208 USA
[4] Argonne Natl Lab, Xray Sci Div, Argonne, IL 60439 USA
基金
美国国家科学基金会;
关键词
noble metals; nanoparticles; DNA; plasmonic materials; metamaterials; electrodynamics simulations; structure-property relationships; DISCRETE-DIPOLE APPROXIMATION; PROGRAMMABLE ATOM EQUIVALENTS; NANOPARTICLE SUPERLATTICES; ELECTROMAGNETIC SCATTERING; SILVER NANOSTRUCTURES; METAL NANOPARTICLES; GOLD NANOPARTICLES; AGGREGATE; CLOAKING; SPHERES;
D O I
10.1002/adma.201302938
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Epsilon-near-zero behavior and an optically metallic response are predicted using electrodynamics simulations in superlattices comprising silver nanoparticles. Programmable DNA-mediated assembly is used to synthesize both silver and binary silver-gold nanoparticle superlattices, which are characterized using small-angle X-ray scattering, transmission electron microscopy, and elemental mapping. © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:653 / 659
页数:7
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