An efficient didehydroxylation method for the biomass-derived polyols glycerol and erythritol. Mechanistic studies of a formic acid-mediated deoxygenation

被引：114
作者：
Arceo, Elena [1 ]
Marsden, Peter [1 ]
Bergman, Robert G. [1 ,2 ]
Ellman, Jonathan A. [1 ]
机构：
[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
[2] Univ Calif Berkeley, Lawrence Berkeley Lab, Div Chem Sci, Berkeley, CA 94720 USA
来源：
CHEMICAL COMMUNICATIONS | 2009年 / 23期
关键词：
ALLYL ALCOHOL; TRANSFORMATION; CHEMICALS; CATALYST; ACROLEIN; DIOLS;
D O I：
10.1039/b907746d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An efficient 1,2-deoxygenation method, involving an unexpected mechanism, was found for simple diols and for biomass-derived polyols (glycerol and erythritol) that results in the conversion of the 1,2-dihydroxy group to a carbon-carbon double bond.
引用
收藏
页码：3357 / 3359
页数：3
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