Sunlight assisted photocatalytic detoxification of sulfur mustard on vanadium ion doped titania nanocatalysts

被引：11

作者：

Ramacharyulu, P. V. R. K. ^{[1
]}

Kumar, J. Praveen ^{[1
]}

Prasad, G. K. ^{[1
]}

Singh, B. ^{[1
]}

Sreedhar, B. ^{[2
]}

Dwivedi, K. ^{[3
]}

机构：

[1] Def Res & Dev Estab, Gwalior 474002, India

[2] Indian Inst Chem Technol, Inorgan & Phys Chem Div, Hyderabad 500007, Andhra Pradesh, India

[3] Jiwaji Univ, Sch Studies Chem, Gwalior 474011, India

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2014年 / 387卷

关键词：

Photocatalysis; Sunlight; Detoxification; Doped nano titania; Sulfur mustard; VISIBLE-LIGHT; TIO2; NANOPARTICLES; DIETHYL SULFIDE; DEGRADATION; DECONTAMINATION; OXIDATION; PHOTOOXIDATION; DESTRUCTION; CATALYST; OXIDES;

D O I：

10.1016/j.molcata.2014.02.022

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Photocatalytic detoxification of sulfur mustard was studied on vanadium ion doped titania nanocatalysts under the irradiation of sunlight. Data obtained on vanadium ion doped titania nanocatalyst was compared with that of bare and commercial TiO2 nanocatalysts. Vanadium ion doped titania nanocatalyst was found to be more active than bare and commercial titania nanocatalysts towards the photocatalytic detoxification of sulfur mustard in ecological sunlight irradiation. 100% of sulfur mustard was found to be detoxified within 180 min on vanadium ion doped TiO2 nanocatalyst Whereas, it took 240 min for bare TiO2 and 420 min for commercial TiO2 nanocatalysts to completely degrade sulfur mustard. Sulfur mustard was found to have degraded to products like acetaldehyde, carbon dioxide, disulfide, sulfoxide and sulfone of sulfur mustard, chloro ethyl vinyl sulfide, chloro ethyl vinyl sulfoxide, etc. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：38 / 44

页数：7

共 41 条

[1] Use of visible light. Second-generation titanium oxide photocatalysts prepared by the application of an advanced metal ion-implantation method [J].