From a Two-Dimensional Supramolecular Network to One-Dimensional Covalent Polymer at the Liquid/Solid Interface: Insight into the Role of the Stoichiometric Ratio of the Precursors

被引：8

作者：

Yu, Yanxia ^{[1
,2
,3
]}

Zheng, Yali ^{[1
]}

Lei, Shengbin ^{[1
,2
,3
]}

机构：

[1] Harbin Inst Technol, Sch Chem & Chem Engn, Harbin 150080, Peoples R China

[2] Tianjin Univ, Tianjin Key Lab Mol Optoelect Sci, Dept Chem, Sch Sci, Tianjin 300072, Peoples R China

[3] Tianjin Univ, Collaborat Innovat Ctr Chem Sci & Engn Tianjin, Tianjin 300072, Peoples R China

来源：

JOURNAL OF PHYSICAL CHEMISTRY C | 2017年 / 121卷 / 01期

基金：

美国国家科学基金会;

关键词：

ORGANIC FRAMEWORKS; SURFACE SYNTHESIS; BUILDING-BLOCKS; FABRICATION; ACTIVATION; REACTIVITY; MOLECULES;

D O I：

10.1021/acs.jpcc.6b11553

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Co-condensation reaction between 2,6-diaminoanthraquinone and aromatic aldehyde at the octanoic acid/highly oriented pyrolitic graphite (HOPG) interface has been studied with scanning tunneling microscopy (STM). We found that the stoichiometric ratio of the precursors plays a vital role in the formation of the assembling structures. By controlling the molar ratio of the amine and aldehyde monomers, either an ordered, hydrogen-bond-stabilized two-dimensional supramolecular network or assembly of one-dimensional covalent polymers can be successfully constructed. The supramolecular network can also be transformed to covalent polymers by annealing the sample to 373 K.

引用

页码：593 / 599

页数：7

共 19 条

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