Luminescent 2D macrocyclic networks based on starburst molecules:: [{Ag(CF3SO3)1.5(tdapb)] and [{Ag(NO3)3(tdapb)]

被引:166
作者
Seward, C
Jia, WL
Wang, RY
Enright, GD
Wang, SN [1 ]
机构
[1] Queens Univ, Dept Chem, Kingston, ON K7L 3N6, Canada
[2] Natl Res Council Canada, Steacie Inst Mol Sci, Ottawa, ON K1A 0R6, Canada
关键词
luminescence; macrocycles; N ligands; silver; supramolecular chemistry;
D O I
10.1002/anie.200353126
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The impact of the anion on the assembly of extended 2D structures has been demonstrated by two distinct luminescent 2D lattices. Shown here is the macrocyclic cloverleaf-shaped cavity obtained from the reaction of a starburst ligand with Ag(NO3). Use of the triflate salt instead results in a honeycomb-shaped cavity.
引用
收藏
页码:2933 / 2936
页数:4
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