2,2':6',2''-terpyridinium trifluoromethane-sulfonate, [terpyH](CF3SO3)

被引：24

作者：

HergoldBrundic, A

Popovic, Z

MatkovicCalogovic, D

机构：

[1] Lab. of Gen. and Inorganic Chemistry, Faculty of Science, University of Zagreb, 10000 Zagreb

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1996年 / 52卷

关键词：

D O I：

10.1107/S0108270196009584

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the title compound, C15H12N3+.CF3O3S-, one terminal pyridine ring of the terpyridinium cation is protonated and forms an intramolecular N--H ... N hydrogen bond of 2.646 (4) Angstrom which stabilizes the cis,trans conformation in contrast to the trans,trans geometry of free terpyridine. An N--H ... O hydrogen bond of 2.817 (5) Angstrom connects the terpyridinium cations and the trifluoromethanesulfonate anions.

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页码：3154 / 3157

页数：4

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