A halochromic stimuli-responsive reversible fluorescence switching 3, 4, 9, 10-perylene tetracarboxylic acid dye for fabricating rewritable platform

被引:47
作者
Hariharan, P. S. [1 ]
Pitchaimani, J. [2 ]
Madhu, Vedichi [2 ]
Anthony, Savarimuthu Philip [1 ]
机构
[1] SASTRA Univ, Sch Chem & Biotechnol, Thanjavur 613401, Tamil Nadu, India
[2] Karunya Univ, Dept Chem, Coimbatore 641114, Tamil Nadu, India
关键词
Halochromism; Fluorescence switching; Rewritable medium; Perylene dye; PERYLENEDIIMIDE; LIGHT; PAPER; WATER;
D O I
10.1016/j.optmat.2016.11.036
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
3, 4, 9, 10-perylene tetracarboxylic acid (PTCA), a strongly fluorescent water soluble dye with halochromic functionality showed pH dependent reversible fluorescence switching. The strong fluorescence of PTCA (Phi(f) = 0.67) in basic medium was completely quenched upon acidification. The fluorescent PTCA has been transferred on to a solid substrate (filter paper and glass plate) that also showed reversible off on fluorescence switching by acid/base and drying/water vapor exposure. The reversible fluorescence switching of PTCA could be of potential interest for fabricating rewritable fluorescent medium. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:53 / 57
页数:5
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