Li-rich anti-perovskite Li3OCl films with enhanced ionic conductivity

被引：156

作者：

Lu, Xujie ^{[1
,2
]}

Wu, Gang ^{[1
]}

Howard, John W. ^{[1
,2
]}

Chen, Aiping ^{[1
]}

Zhao, Yusheng ^{[2
]}

Daemen, Luke L. ^{[1
]}

Jia, Quanxi ^{[1
]}

机构：

[1] Los Alamos Natl Lab, Los Alamos, NM 87545 USA

[2] Univ Nevada, Las Vegas, NV 89154 USA

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 78期

关键词：

BATTERY; THIN; ELECTROLYTES;

D O I：

10.1039/c4cc05372a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Anti-perovskite solid electrolyte films were prepared by pulsed laser deposition, and their room-temperature ionic conductivity can be improved by more than an order of magnitude in comparison with its bulk counterpart. The cyclability of Li3OCl films in contact with lithium was evaluated using a Li/Li3OCl/Li symmetric cell, showing self-stabilization during cycling test.

引用

页码：11520 / 11522

页数：3

共 19 条

[1] Phase Stability and Transport Mechanisms in Antiperovskite Li3OCl and Li3OBr Superionic Conductors [J].

Emly, Alexandra ;

Kioupakis, Emmanouil ;

Van der Ven, Anton .

CHEMISTRY OF MATERIALS, 2013, 25 (23) :4663-4670

[2] Challenges in the development of advanced Li-ion batteries: a review [J].

Etacheri, Vinodkumar ;

Marom, Rotem ;

Elazari, Ran ;

Salitra, Gregory ;

Aurbach, Doron .

ENERGY & ENVIRONMENTAL SCIENCE, 2011, 4 (09) :3243-3262

[3] The Li-Ion Rechargeable Battery: A Perspective [J].

Goodenough, John B. ;

Park, Kyu-Sung .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (04) :1167-1176

[4] Challenges for Rechargeable Li Batteries [J].

Goodenough, John B. ;

Kim, Youngsik .

CHEMISTRY OF MATERIALS, 2010, 22 (03) :587-603

[5] Experimental visualization of lithium conduction pathways in garnet-type Li7La3Zr2O12 [J].

Han, Jiantao ;

Zhu, Jinlong ;

Li, Yutao ;

Yu, Xiaohui ;

Wang, Shanmin ;

Wu, Gang ;

Xie, Hui ;

Vogel, Sven C. ;

Izumi, Fujio ;

Momma, Koichi ;

Kawamura, Yukihiko ;

Huang, Yunhui ;

Goodenough, John B. ;

Zhao, Yusheng .

CHEMICAL COMMUNICATIONS, 2012, 48 (79) :9840-9842

[6] Thin, Flexible Secondary Li-Ion Paper Batteries [J].

Hu, Liangbing ;

Wu, Hui ;

La Mantia, Fabio ;

Yang, Yuan ;

Cui, Yi .

ACS NANO, 2010, 4 (10) :5843-5848

[7] Fast Lithium-Ion Conducting Thin-Film Electrolytes Integrated Directly on Flexible Substrates for High-Power Solid-State Batteries [J].

Ihlefeld, Jon F. ;

Clem, Paul G. ;

Doyle, Barney L. ;

Kotula, Paul G. ;

Fenton, Kyle R. ;

Apblett, Christopher A. .

ADVANCED MATERIALS, 2011, 23 (47) :5663-+

[8] Bendable Inorganic Thin-Film Battery for Fully Flexible Electronic Systems [J].

Koo, Min ;

Park, Kwi-Il ;

Lee, Seung Hyun ;

Suh, Minwon ;

Jeon, Duk Young ;

Choi, Jang Wook ;

Kang, Kisuk ;

Lee, Keon Jae .

NANO LETTERS, 2012, 12 (09) :4810-4816

[9] Compatibility of Li7La3Zr2O12 Solid Electrolyte to All-Solid-State Battery Using Li Metal Anode [J].

Kotobuki, Masashi ;

Munakata, Hirokazu ;

Kanamura, Kiyoshi ;

Sato, Yosuke ;

Yoshida, Toshihiro .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2010, 157 (10) :A1076-A1079

[10] Research on Advanced Materials for Li-ion Batteries [J].

Li, Hong ;

Wang, Zhaoxiang ;

Chen, Liquan ;

Huang, Xuejie .

ADVANCED MATERIALS, 2009, 21 (45) :4593-4607

← 1 2 →