Highly Sensitive and Selective Fluorometric/Electrochemical Dual-Channel Sensors for TNT and DNT Explosives

被引：28

作者：

Ma, Hongwei ^{[1
]}

Yao, Liang ^{[1
]}

Li, Peng ^{[1
]}

Ablikim, Obolda ^{[1
]}

Cheng, Yunfei ^{[2
]}

Zhang, Ming ^{[1
]}

机构：

[1] Jilin Univ, State Key Lab Supramol Struct & Mat, Changchun 130012, Peoples R China

[2] Minist Publ Secur, Res Inst 3, Shanghai 200031, Peoples R China

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2014年 / 20卷 / 37期

基金：

美国国家科学基金会;

关键词：

electrochemical sensors; electropolymerization; fluorescent films; fluorescent sensors; TNT/DNT; AGGREGATION-INDUCED EMISSION; ELECTROCHEMICAL SENSORS; FLUORESCENCE DETECTION; CONJUGATED POLYMERS; CARBON NANOTUBES; CHEMICAL SENSORS; FILMS; COMPOSITES; VAPORS;

D O I：

10.1002/chem.201402206

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel electro-active compound, TCAC, is synthesized and its electrochemical polymerized film is used to detect 2,4,6-trinitrotoluene (TNT) and 2,4-dinitrotoluene (DNT) explosives through a fluorometric/electrochemical dual-channel sensor with high sensitivity and selectivity. In particular, the electrochemical sensor for the analysis of TNT had an enhanced sensitivity of 0.5 mu M. The detection limit of the sensor was calculated to be 15 nM.

引用

页码：11655 / 11658

页数：4

共 35 条

[1] Electrochemical Sensors Based on Carbon Nanotubes [J].

Ahammad, A. J. Saleh ;

Lee, Jae-Joon ;

Rahman, Md. Aminur .

SENSORS, 2009, 9 (04) :2289-2319

[2] High-speed fluorescence detection of explosives-like vapors [J].

Albert, KJ ;

Walt, DR .

ANALYTICAL CHEMISTRY, 2000, 72 (09) :1947-1955

[3] Dendrimers Designed for Functions: From Physical, Photophysical, and Supramolecular Properties to Applications in Sensing, Catalysis, Molecular Electronics, Photonics, and Nanomedicine [J].

Astruc, Didier ;

Boisselier, Elodie ;

Ornelas, Catia .

CHEMICAL REVIEWS, 2010, 110 (04) :1857-1959

[4] Electrochemical sensors [J].

Bakker, E .

ANALYTICAL CHEMISTRY, 2004, 76 (12) :3285-3298

[5] Disposable screen-printed sensors for the electrochemical detection of TNT and DNT [J].

Caygill, J. Sarah ;

Collyer, Stuart D. ;

Holmes, Joanne L. ;

Davis, Frank ;

Higson, Seamus P. J. .

ANALYST, 2013, 138 (01) :346-352

[6] Graphene Oxide: Preparation, Functionalization, and Electrochemical Applications [J].

Chen, Da ;

Feng, Hongbin ;

Li, Jinghong .

CHEMICAL REVIEWS, 2012, 112 (11) :6027-6053

[7] Palladium-Catalyzed Synthesis of 7,9-Diaryl-8H-acenaphtho[1,2-c]pyrroles and Their Application in Explosives Detection [J].

Chen, Xiaopeng ;

Jin, Jisong ;

Wang, Yanguang ;

Lu, Ping .

CHEMISTRY-A EUROPEAN JOURNAL, 2011, 17 (36) :9920-9923

[8] Aggregation induced emission and amplified explosive detection of tetraphenylethylene-substituted polycarbazoles [J].

Dong, Wenyue ;

Fei, Teng ;

Palma-Cando, Alex ;

Scherf, Ullrich .

POLYMER CHEMISTRY, 2014, 5 (13) :4048-4053

[9] The new age of carbon nanotubes: An updated review of functionalized carbon nanotubes in electrochemical sensors [J].

Gao, Chao ;

Guo, Zheng ;

Liu, Jin-Huai ;

Huang, Xing-Jiu .

NANOSCALE, 2012, 4 (06) :1948-1963

[10] Cross-Linked Multifunctional Conjugated Polymers Prepared by In Situ Electrochemical Deposition for a Highly-Efficient Blue-Emitting and Electron-Transport Layer [J].

Gu, Cheng ;

Dong, Wenyue ;

Yao, Liang ;

Lv, Ying ;

Zhang, Zhongbo ;

Lu, Dan ;

Ma, Yuguang .

ADVANCED MATERIALS, 2012, 24 (18) :2413-2417

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