Benefits of very thin PCBM and LiF layers for solution-processed p-i-n perovskite solar cells

被引：626
作者：
Seo, Jangwon [1 ]
Park, Sangman [1 ]
Kim, Young Chan [1 ]
Jeon, Nam Joong [1 ]
Noh, Jun Hong [1 ]
Yoon, Sung Cheol [1 ]
Seok, Sang Il [1 ,2 ]
机构：
[1] Korea Res Inst Chem Technol, Div Adv Mat, Taejon 305600, South Korea
[2] Sungkyunkwan Univ, Dept Energy Sci, Suwon 440746, South Korea
来源：
ENERGY & ENVIRONMENTAL SCIENCE | 2014年 / 7卷 / 08期
基金：
新加坡国家研究基金会;
关键词：
HIGH-EFFICIENCY; LOW-COST; ELECTRON; PERFORMANCE; TRIHALIDE; LENGTHS; ROUTE;
D O I：
10.1039/c4ee01216j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Highly efficient p-i-n perovskite solar cells employing a flat and thick CH(3)NH(3)Pbl(3) film and a thin PCBM film are fabricated by the solution-process at low temperature. Through attainment of optimized PCBM thickness and insertion of the LW interlayer, the unit cell shows 14.1% of overall power conversion efficiency (PCE) with a J(sc) of 20.7 mA cm(-2), a V-oc of 0.866 V, and a FF of 78.3% under AM 1.5G 100 mW cm(-2) conditions, while a larger area 10 cell serially connected module (10 x 10 cm(2)) shows an 8.7% PCE. These PCE values are the highest reported to date for the planar perovskite-PCBM solar cells.
引用
收藏
页码：2642 / 2646
页数：5
相关论文
共 50 条
  • [1] Solution-processed inorganic copper(I) thiocyanate (CuSCN) hole transporting layers for efficient p-i-n perovskite solar cells
    Zhao, K.
    Munir, R.
    Yan, B.
    Yang, Y.
    Kim, T.
    Amassian, A.
    JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (41) : 20554 - 20559
  • [2] p-i-n Structured Semitransparent Perovskite Solar Cells with Solution-Processed Electron Transport Layer
    Guchhait, Asim
    Dalapati, Goutam Kumar
    Sonar, Prashant
    Gopalan, Saianand
    Bin Suhaimi, Firdaus
    Das, Tapas
    Dutt, V. G. Vasavi
    Mishra, Nimai
    Mahata, Chandreswar
    Kumar, Avishek
    Ramakrishna, Seeram
    JOURNAL OF ELECTRONIC MATERIALS, 2021, 50 (10) : 5732 - 5739
  • [3] Enhanced performance of perovskite solar cells with solution-processed n-doping of the PCBM interlayer
    Bae, Jun-Ho
    Noh, Yong-Jin
    Kang, Minji
    Kim, Dong-Yu
    Kim, Hyun-Bin
    Oh, Seung-Hwan
    Yun, Jin-Mun
    Na, Seok-In
    RSC ADVANCES, 2016, 6 (69) : 64962 - 64966
  • [4] Solution-Processed Laminated Perovskite Layers for High-Performance Solar Cells
    Wang, Yangyang
    Li, Tianhao
    Li, Zengrong
    Wang, Sen
    Deng, Xianyu
    ADVANCED FUNCTIONAL MATERIALS, 2019, 29 (45)
  • [5] Biphenyl Triarylamine Hole Transport Material for Highly Efficient and Low-Temperature Solution-Processed p-i-n Perovskite Solar Cells
    Meng, Juan
    Song, Dandan
    Xu, Zheng
    Zhao, Suling
    Qiao, Bo
    Huang, Di
    Li, Yang
    Yuan, Binbin
    JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY, 2018, 18 (11) : 7374 - 7379
  • [6] Efficient indoor p-i-n hybrid perovskite solar cells using low temperature solution processed NiO as hole extraction layers
    Jagadamma, Lethy Krishnan
    Blaszczyk, Oskar
    Sajjad, Muhammad T.
    Ruseckas, Arvydas
    Samuel, Ifor D. W.
    SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2019, 201
  • [7] Cross-Linkable Fullerene Derivatives for Solution-Processed n-i-p Perovskite Solar Cells
    Wojciechowski, Konrad
    Ramirez, Ivan
    Gorisse, Therese
    Dautel, Olivier
    Dasari, Raghunath
    Sakai, Nobuya
    Hardigree, Josue Martinez
    Song, Seulki
    Marder, Seth
    Riede, Moritz
    Wantz, Guillaume
    Snaith, Henry J.
    ACS ENERGY LETTERS, 2016, 1 (04): : 648 - 653
  • [8] Photo-Crosslinkable Naphthalene Diimide Polymer for Solution-Processed n-i-p Perovskite Solar Cells
    Shi, Yangwei
    McCarthy, Declan P.
    Lungwitz, Dominique
    Jiang, Fangyuan
    Taddei, Margherita
    Contreras, Hannah
    Lin, Yujing
    Mohapatra, Aiswarya Abhisek
    Tang, Kan
    Zhang, Yadong
    Barlow, Stephen
    Kahn, Antoine
    Marder, Seth R.
    Ginger, David S.
    CHEMISTRY OF MATERIALS, 2024, 36 (02) : 795 - 802
  • [9] High performance planar p-i-n perovskite solar cells with crown-ether functionalized fullerene and LiF as double cathode buffer layers
    Liu, Xiaodong
    Lei, Ming
    Zhou, Yi
    Song, Bo
    Li, Yongfang
    APPLIED PHYSICS LETTERS, 2015, 107 (06)
  • [10] Modification of low temperature solution-processed NiO with Me-4PACz for efficient and air-stable p-i-n perovskite solar cells
    Lee, Ga-Eun
    Baek, Se-Yeong
    Kim, Seok-Soon
    JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2024, 28 (08) : 2679 - 2687
12345