Electron-deficient truxenone derivatives and their use in organic photovoltaics

被引：30

作者：

Nielsen, Christian B. ^{[1
,2
]}

Voroshazi, Eszter ^{[3
]}

Holliday, Sarah ^{[1
,2
]}

Cnops, Kjell ^{[3
,4
]}

Cheyns, David ^{[3
]}

McCulloch, Iain ^{[1
,2
]}

机构：

[1] Univ London Imperial Coll Sci Technol & Med, Dept Chem, London SW7 2AZ, England

[2] Univ London Imperial Coll Sci Technol & Med, Ctr Plast Elect, London SW7 2AZ, England

[3] IMEC, B-3001 Heverlee, Belgium

[4] Katholieke Univ Leuven, ESAT, B-3001 Heverlee, Belgium

来源：

JOURNAL OF MATERIALS CHEMISTRY A | 2014年 / 2卷 / 31期

基金：

英国工程与自然科学研究理事会;

关键词：

AXIS VECTOR ANALYSIS; SOLAR-CELLS; NON-FULLERENE; ACCEPTORS; HETEROJUNCTION; MOLECULES; ORIENTATION;

D O I：

10.1039/c4ta01653j

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A series of electron-deficient truxenone derivatives are investigated as fullerene alternatives in organic photovoltaic applications. These new electron-accepting molecules have easily tunable absorption profiles, more than ten-fold higher absorptivities than PCBM, slightly higher electron affinities than PCBM and clearly defined and highly reversible reductive characteristics. Fabrication of efficient bilayer solar cells with a subphthalocyanine (SubPc) donor illustrates the promise of this class of materials as electron acceptors in organic solar cells.

引用

页码：12348 / 12354

页数：7

共 22 条

[1]

[Anonymous], 1991, MODERN MOL PHOTOCHEM

[2] Small-Molecule, Nonfullerene Acceptors for Polymer Bulk Heterojunction Organic Photovoltaics [J].

Anthony, John E. .

CHEMISTRY OF MATERIALS, 2011, 23 (03) :583-590

[3] n-Type Organic Semiconductors in Organic Electronics [J].

Anthony, John E. ;

Facchetti, Antonio ;

Heeney, Martin ;

Marder, Seth R. ;

Zhan, Xiaowei .

ADVANCED MATERIALS, 2010, 22 (34) :3876-3892

[4] Organic tandem solar cells with complementary absorbing layers and a high open-circuit voltage [J].

Cheyns, D. ;

Rand, B. P. ;

Heremans, P. .

APPLIED PHYSICS LETTERS, 2010, 97 (03)

[5] 25th Anniversary Article: A Decade of Organic/Polymeric Photovoltaic Research [J].

Dou, Letian ;

You, Jingbi ;

Hong, Ziruo ;

Xu, Zheng ;

Li, Gang ;

Street, Robert A. ;

Yang, Yang .

ADVANCED MATERIALS, 2013, 25 (46) :6642-6671

[6] Recent advances of non-fullerene, small molecular acceptors for solution processed bulk heterojunction solar cells [J].

Eftaiha, Ala'a F. ;

Sun, Jon-Paul ;

Hill, Ian G. ;

Welch, Gregory C. .

JOURNAL OF MATERIALS CHEMISTRY A, 2014, 2 (05) :1201-1213

[7] Electronic structure and spectral, of ruthenium diimine complexes by density functional theory and INDO/S. Comparison of the two methods [J].

Gorelsky, SI ;

Lever, ABP .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2001, 635 (1-2) :187-196

[8] PI-ORBITAL CONJUGATION AND REHYBRIDIZATION IN BRIDGED ANNULENES AND DEFORMED MOLECULES IN GENERAL - PI-ORBITAL AXIS VECTOR ANALYSIS [J].

HADDON, RC ;

SCOTT, LT .

PURE AND APPLIED CHEMISTRY, 1986, 58 (01) :137-142

[9] MEASURE OF NONPLANARITY IN CONJUGATED ORGANIC-MOLECULES - WHICH STRUCTURALLY CHARACTERIZED MOLECULE DISPLAYS THE HIGHEST DEGREE OF PYRAMIDALIZATION [J].

HADDON, RC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (09) :3385-3389

[10] HYBRIDIZATION AND THE ORIENTATION AND ALIGNMENT OF PI-ORBITALS IN NONPLANAR CONJUGATED ORGANIC-MOLECULES - PI-ORBITAL AXIS VECTOR ANALYSIS (POAV2) [J].

HADDON, RC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (11) :2837-2842

← 1 2 3 →