Enhanced laser scribed flexible graphene-based micro-supercapacitor performance with reduction of carbon nanotubes diameter

被引：133

作者：

Wen, Fusheng ^{[1
]}

Hao, Chunxue ^{[1
]}

Xiang, Jianyong ^{[1
]}

Wang, Limin ^{[1
]}

Hou, Hang ^{[1
]}

Su, Zhibin ^{[1
]}

Hu, Wentao ^{[1
]}

Liu, Zhongyuan ^{[1
]}

机构：

[1] Yanshan Univ, State Key Lab Metastable Mat Sci & Technol, Qinhuangdao 066004, Peoples R China

来源：

CARBON | 2014年 / 75卷

基金：

中国国家自然科学基金;

关键词：

ALL-SOLID-STATE; GRAPHITE OXIDE; CHIP; ELECTRODES; NANOWIRES;

D O I：

10.1016/j.carbon.2014.03.058

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

By making use of the induced transformation of graphite oxide (GO) to laser scribed graphene (LSG), the coated layers of GO/carbon nanotubes (CNTs) hybrid powders on flexible polyethylene terephthalate sheets were patterned into LSG/CNTs micro-supercapacitors (LSG/CNTs-MSCs). In the presence of CNTs with a smaller diameter, the laser-scribed LSG/CNTs-MSC was found to yield the better energy storage performance. This dependence on the CNT diameter can be attributed to the role of CNTs in prevention of restacking of LSG layers and thus the increase of ion-accessible surface area. The CNTs with a smaller diameter can be more easily inserted between the LSG layers, thus inhibiting the restacldng phenomenon more effectively. By using the single-wall CNTs (SWCNTs) of 1-2 nm diameter, the laser-scribed LSG/SWCNTs-MSC was observed to exhibit the best electrochemical properties: The volumetric capacitance of 3.10 F cm(-3) at a current density of 1000 mA cm(-3), the volumetric energy density of 0.84 mW h cm(-3) and power density of 1.0W cm(-3), and long-term cycling stability. (C) 2014 Elsevier Ltd. All rights reserved.

引用

页码：236 / 243

页数：8

共 34 条

[11] A high-performance current collector-free flexible in-plane micro-supercapacitor based on a highly conductive reduced graphene oxide film [J].

Wu, Mingmao ;

Li, Yingru ;

Yao, Bowen ;

Chen, Ji ;

Li, Chun ;

Shi, Gaoquan .

JOURNAL OF MATERIALS CHEMISTRY A, 2016, 4 (41) :16213-16218

[12] Direct synthesis method of metal oxide and 3D graphene composite by laser irradiation and its applications in flexible micro-supercapacitor [J].

Sain, Sourav ;

Roy, Souradeep ;

Mathur, Ashish ;

Roy, Susanta Sinha .

JOURNAL OF ENERGY STORAGE, 2024, 99

[13] Sputtered thin film deposited laser induced graphene based novel micro-supercapacitor device for energy storage application [J].

Sain, Sourav ;

Chowdhury, Suman ;

Maity, Sayantan ;

Maity, Gurupada ;

Roy, Susanta Sinha .

SCIENTIFIC REPORTS, 2024, 14 (01)

[14] Enhanced Electrochemical Performance of Micro-Supercapacitors Via Laser-Scribed Cobalt/Reduced Graphene Oxide Hybrids [J].

Lee, Sang Hwa ;

Lee, Jungjun ;

Jung, Jaemin ;

Cho, A. Ra ;

Jeong, Jae Ryeol ;

Cu Dang Van ;

Nah, Junghyo ;

Lee, Min Hyung .

ACS APPLIED MATERIALS & INTERFACES, 2021, 13 (16) :18821-18828

[15] Flexible and Wire-Shaped Micro-Supercapacitor Based on Ni(OH)2-Nanowire and Ordered Mesoporous Carbon Electrodes [J].

Dong, Xiaoli ;

Guo, Ziyang ;

Song, Yanfang ;

Hou, Mengyan ;

Wang, Jianqiang ;

Wang, Yonggang ;

Xia, Yongyao .

ADVANCED FUNCTIONAL MATERIALS, 2014, 24 (22) :3405-3412

[16] Facile Fabrication of Flexible Graphene-Based Micro-Supercapacitors with Ultra-High Areal Performance [J].

Zhao, Yirong ;

Du, Jingwei ;

Li, Yunxia ;

Li, Xiaopeng ;

Zhang, Chaoyue ;

Zhang, Xudong ;

Zhang, Zhenxing ;

Zhou, Jinyuan ;

Pan, Xiaojun ;

Xie, Erqing .

ACS APPLIED ENERGY MATERIALS, 2020, 3 (09) :8415-8422

[17] Electrochemical performance of flexible poly(ethylene terephthalate) (PET) supercapacitor based on reduced graphene oxide (rGO)/single-wall carbon nanotubes (SWNTs) [J].

Kim, Byung Chul ;

Jeong, Hyeon Taek ;

Raj, C. Justin ;

Kim, Yong-Ryeol ;

Cho, Bo-Bae ;

Yu, Kook Hyun .

SYNTHETIC METALS, 2015, 207 :116-121

[18] Effects of amount of graphene oxide and the times of LightScribe on the performance of all-solid-state flexible graphene-based micro-supercapacitors [J].

Cai, Fenglian ;

Tao, Cheng-an ;

Li, Yujiao ;

Yin, Wenchang ;

Wang, Xueye ;

Wang, Jianfang .

MATERIALS RESEARCH EXPRESS, 2017, 4 (03)

[19] A three-dimensional flexible supercapacitor with enhanced performance based on lightweight, conductive graphene-cotton fabric electrode [J].

Zhou, Qianlong ;

Ye, Xingke ;

Wan, Zhongquan ;

Jia, Chunyang .

JOURNAL OF POWER SOURCES, 2015, 296 :186-196

[20] Preparation of a graphene-based composite aerogel and the effects of carbon nanotubes on preserving the porous structure of the aerogel and improving its capacitor performance [J].

Ma, Zhihua ;

Zhao, Xiaowei ;

Gong, Chunhong ;

Zhang, Jingwei ;

Zhang, Jiwei ;

Gu, Xiufang ;

Tong, Lei ;

Zhou, Jingfang ;

Zhang, Zhijun .

JOURNAL OF MATERIALS CHEMISTRY A, 2015, 3 (25) :13445-13452

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