Glycerol esters from the reaction of glycerol with dicarboxylic acid esters

被引：13
作者：
Cho, Gladys H. P.
Yeong, S. K.
Ooi, T. L.
Chuah, C. H.
机构：
[1] AOTD MPOB, Bandar Baru Bangi 43650, Selangor Darul, Malaysia
[2] Univ Malaya, Fac Sci, Dept Chem, Kuala Lumpur, Malaysia
来源：
JOURNAL OF SURFACTANTS AND DETERGENTS | 2006年 / 9卷 / 02期
关键词：
diglycerol ester; dimethyl ester; glycerol; monoglycerol ester;
D O I：
10.1007/s11743-006-0384-9
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Mono- and di-esterified glycerols were synthesized by the base catalyzed reaction of glycerol with aliphatic dicarboxylic acid esters (C-2-C-9): 2,3-dihydroxy-propyl oxalate (2), 1,3 dioxalyloxy propan-2-ol (3), 1,3-dimethoxyoxalyloxy propan-2-ol (5), 2,3-dihydroxy-propyl malonate (6), 2,3-dihydroxy-propyl methyl malonate (7), 2,3-dihydroxy-propyl methyl succinate (8), 1,3-dimethoxysuccinyloxy propan-2-ol (9), 2,3-dihydroxy-propyl methyl glutarate (10), 1,3-dimethoxyglutaryloxy propan-2-ol (11), 2,3-dihydroxy-propyl methyl azelate (14), and 1,3-dimethoxyazelyloxy propan-2-ol (15). Their structures were elucidated by spectrometric methods. Compounds 8, 10, 2,3-dihydroxy-propl methyl adipate (12) and 14 were found to possess surface active properties and the ability to reduce the interfacial tension between paraffin and water.
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收藏
页码：147 / 152
页数：6
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