Mixed-Lanthanide Metal Organic Frameworks with Tunable Color and White Light Emission

被引：73

作者：

Gai, Yanli ^{[1
]}

Guo, Qin ^{[1
]}

Xiong, Kecai ^{[1
]}

Jiang, Feilong ^{[2
]}

Li, Chenyuan ^{[1
]}

Li, Xin ^{[1
]}

Chen, Yan ^{[1
]}

Zhu, Chengyuan ^{[1
]}

Huang, Qing ^{[1
]}

Yao, Rui ^{[1
]}

Hong, Maochun ^{[2
]}

机构：

[1] Jiangsu Normal Univ, Sch Chem & Chem Engn, Jiangsu Key Lab Green Synthet Chem Funct Mat, Xuzhou 221116, Peoples R China

[2] Univ Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Coal Ethylene Glycol, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China

来源：

CRYSTAL GROWTH & DESIGN | 2017年 / 17卷 / 03期

基金：

中国国家自然科学基金;

关键词：

INTRAMOLECULAR ENERGY-TRANSFER; COORDINATION POLYMERS; HIGHLY LUMINESCENT; EUROPIUM COMPLEX; LIGAND; ACID; DIVERSITIES; THERMOMETER; SERIES; MOFS;

D O I：

10.1021/acs.cgd.6b01541

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three isostructural lanthanide metal organic frameworks (Ln-MOFs, Ln = Eu3+, Tb3+, Dy3+) containing P-terphenyl-2,2",4,4"-tetracarboxylate ligand (H4L) with red, green, and blue luminescence were solvothermally synthesized. Thus, a series of mixed Ln-MOFs, (EuxTbyDy1-x-y) (HL) (H2O) (DEF) (DEF, N,N-diethylformamide), were designed and obtained, which displayed highly temperature-tuned emission in the visible region, including white light emission. Additionally, tunable luminescence can also be achieved by changing the excitation wavelength.

引用

页码：940 / 944

页数：5

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