The structure and corrosion barrier performance of nanocrystalline zirconia electrodeposited coating

被引:36
作者
Setare, E. [1 ]
Raeissi, K. [1 ]
Golozar, M. A. [1 ]
Fathi, M. H. [1 ]
机构
[1] Isfahan Univ Technol, Dept Mat Engn, Esfahan 8415683111, Iran
关键词
Stainless steel; EIS; Polarization; SEM; XRD; ELECTROLYTIC DEPOSITION; STAINLESS-STEELS; ELECTROCHEMICAL DEPOSITION; PASSIVE FILMS; OXIDE; RESISTANCE; ALLOYS; PULSE; CR;
D O I
10.1016/j.corsci.2009.05.004
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Zirconia (ZrO2) with the thickness of about 1.5 mu m were prepared onto mechanically polished and electrochemically prepared surfaces of 316L stainless steel by direct and pulse current electrodeposition followed by annealing. The ZrO2 coatings were nanocrystalline with a tetragonal crystallographic structure. The coatings produced by direct current showed a heterogeneous structure in "cracked-mud" appearance. Pulse current produced a more uniform and dense coating with a strong mechanical barrier property. It also revealed a passive behavior on the Tafel polarization plot. The ZrO2 coatings produced on electrochemically prepared Surfaces showed a very small passive region on Tafel polarization curves. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1802 / 1808
页数:7
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