Highly active InOx/TUD-1 catalyst towards Baeyer-Villiger oxidation of cyclohexanone using molecular oxygen and benzaldehyde

被引：19

作者：

Kumar, Rawesh ^{[1
]}

Das, Prangya Paramita ^{[1
]}

Al-Fatesh, Ahmed Sadeq ^{[2
]}

Fakeeha, Anis Hamza ^{[2
]}

Pandey, Jai Krishna ^{[3
]}

Chowdhury, Biswajit ^{[1
]}

机构：

[1] Indian Sch Mines, Dept Appl Chem, Dhanbad 826004, Bihar, India

[2] King Saud Univ, Dept Chem Engn, Coll Engn, Riyadh 11421, Saudi Arabia

[3] Cent Inst Min & Fuel Res, Dhanbad, Bihar, India

来源：

CATALYSIS COMMUNICATIONS | 2016年 / 74卷

关键词：

InOx/TUD-1; Cyclohexanone; Benzaldehyde; Baeyer-Villiger; Molecular oxygen; KETONES; EPOXIDATION; CONVERSION; STYRENE; TUD-1;

D O I：

10.1016/j.catcom.2015.11.007

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

InOx/TUD-1 is prepared by sal-gel method and characterized by different techniques. On the basis of different characterization results it is found that spongy porous InOx/TUD-1 (In/Si = 8/100) matrix contains small crystallite of indium oxide in +3 oxidation state. InOx/RID-1 (In/Si = 8/100) catalyst shows good catalytic results for Baeyer-Villiger oxidation of cyclic ketones using molecular oxygen and sacrificial reagent benzaldehyde. The cyclohexanone conversion was found 100% with e-caprolactone selectivity 100% using polar aprotic solvents e.g. dichloroethane, acetonitrile and benzonitrile in the presence of molecular oxygen. (C) 2015 Published by Elsevier B.V.

引用

页码：80 / 84

页数：5

共 22 条

[1] Indium incorporated silica from rice husk and its catalytic activity
Ahmed, Adil Elhag
Adam, Farook
[J]. MICROPOROUS AND MESOPOROUS MATERIALS, 2007, 103 (1-3) : 284 - 295
[2] Baeyer A., 1899, BER DTSCH CHEM GES, V32, P3625, DOI DOI 10.1002/CBER.189903203151
[3] Fe, Co and Cu-incorporated TUD-1:: Synthesis, characterization and catalytic performance in N2O decomposition and cyclohexane oxidation
Hamdy, MS
Mul, G
Wei, W
Anand, R
Hanefeld, U
Jansen, JC
Moulijn, JA
[J]. CATALYSIS TODAY, 2005, 110 (3-4) : 264 - 271
[4] Aerobic Baeyer-Villiger Oxidation of Cyclic Ketones over Metalloporphyrins Bridged Periodic Mesoporous Organosilica
Jeong, Eun-Young
Ansari, Mohd Bismillah
Park, Sang-Eon
[J]. ACS CATALYSIS, 2011, 1 (08): : 855 - 863
[5] BAEYER-VILLIGER OXIDATION OF KETONES USING MOLECULAR-OXYGEN AND BENZALDEHYDE IN THE ABSENCE OF METAL-CATALYSTS
KANEDA, K
UENO, S
IMANAKA, T
SHIMOTSUMA, E
NISHIYAMA, Y
ISHII, Y
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1994, 59 (11) : 2915 - 2917
[6] CATALYSIS OF TRANSITION METAL-FUNCTIONALIZED HYDROTALCITES FOR THE BAEYER-VILLIGER OXIDATION OF KETONES IN THE PRESENCE OF MOLECULAR-OXYGEN AND BENZALDEHYDE
KANEDA, K
UENO, S
IMANAKA, T
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1995, 102 (03) : 135 - 138
[7] Iron-containing MCM-41 catalysts for Baeyer-Villiger oxidation of ketones using molecular oxygen and benzaldehyde
Kawabata, T
Ohishi, Y
Itsuki, S
Fujisaki, N
Shishido, T
Takaki, K
Zhang, QH
Wang, Y
Takehira, K
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2005, 236 (1-2) : 99 - 106
[8] Bismuth supported SBA-15 catalyst for vapour phase Beckmann rearrangement reaction of cyclohexanone oxime to ε-caprolactam
Kumar, Rawesh
Enjamuri, Nagasuresh
Pandey, J. K.
Sen, Debasis
Mazumder, S.
Bhaumik, Asim
Chowdhury, Biswajit
[J]. APPLIED CATALYSIS A-GENERAL, 2015, 497 : 51 - 57
[9] Acid-Catalysed Conversion of Saccharides into Furanic Aldehydes in the Presence of Three-Dimensional Mesoporous Al-TUD-1
Lima, Sergio
Antunes, Margarida M.
Fernandes, Auguste
Pillinger, Martyn
Ribeiro, Maria Filipa
Valente, Anabela A.
[J]. MOLECULES, 2010, 15 (06): : 3863 - 3877
[10] Synthesis, characterization of Ga-TUD-1 catalyst and its activity towards styrene epoxidation reaction
Mandal, Sandip
SinhaMahapatra, Apurba
Rakesh, Batchu
Kumar, Rawesh
Panda, Asit
Chowdhury, Biswajit
[J]. CATALYSIS COMMUNICATIONS, 2011, 12 (08) : 734 - 738

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