Multianvil high-pressure synthesis of Dy4B6O15:: The first oxoborate with edge-sharing BO4 tetrahedra

被引：239
作者：
Huppertz, H [1 ]
von der Eltz, B [1 ]
机构：
[1] Univ Munich, Dept Chem, D-81377 Munich, Germany
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 32期
关键词：
D O I：
10.1021/ja017691z
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In all known oxoborates the linkage of BO3 and BO4 groups is performed via common corners. Here we present the high-pressure/high-temperature synthesis of Dy4B6O15, which is the first oxoborate exhibiting edge-sharing BO4 tetrahedra. Copyright © 2002 American Chemical Society.
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页码：9376 / 9377
页数：2
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