Kinetics of oxidation of vanadyl acetylacetonate by oxygen in methanolic solution

被引：19

作者：

Grybos, R ^{[1
]}

Samotus, A ^{[1
]}

Popova, N ^{[1
]}

Bogolitsyn, K ^{[1
]}

机构：

[1] ARKHANGELSK STATE ENGN UNIV,FAC CHEM,ARKHANGELSK 163007,RUSSIA

来源：

TRANSITION METAL CHEMISTRY | 1997年 / 22卷 / 01期

关键词：

Oxidation; Oxygen; Physical Chemistry; Inorganic Chemistry; Vanadium;

D O I：

10.1023/A:1018426004961

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The kinetics of oxidation of vanadyl acetylacetonate to VO(OH)(OMe)(acac) by molecular O-2 in MeOH have been studied spectrophotometrically. The reaction, which is pseudo first-order with respect to [VO(acac)(2)] and [O-2], is inhibited by Hacac and a vanadium(V) complex. The rate data were used to calculate the thermodynamic activation parameters. A mechanism for the reaction is discussed.

引用

页码：61 / 64

页数：4

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