Azobenzenes and heteroaromatic nitrogen cyclopalladated complexes for advanced applications

被引：169

作者：

Ghedini, Mauro ^{[1
]}

Aiello, Iolinda ^{[1
]}

Crispini, Alessandra ^{[1
]}

Golemme, Attilio ^{[1
]}

La Deda, Massimo ^{[1
]}

Pucci, Daniela ^{[1
]}

机构：

[1] Univ Calabria, Ctr Eccellenza CEMIF CAL & LASCAMM, CR,Dipartimento Chim, INSTM,Unita INSTM Calabria, I-87036 Arcavacata Di Rende, CS, Italy

来源：

COORDINATION CHEMISTRY REVIEWS | 2006年 / 250卷 / 11-12期

关键词：

cyclopalladated complexes; molecular materials; liquid crystals; luminescence; photoconductivity; photorefractivity;

D O I：

10.1016/j.ccr.2005.12.011

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The five-membered "(C,N)Pd" metallacycle is a structural feature common to a number of stable photoactive molecular materials. This review is centred on the connection among molecular geometries, types of ligand and photophysical, optical, thermal and electrooptical properties of several series of dinuclear and mononuclear cyclopalladated species, based on HC,N ligands (HC,N = azobenzenes or nitrogen containing heteroaromatic ligands). In the discussion, some representative examples of complexes featuring an useful set of physical properties, were selected and divided into different classes, depending on the nature of the ancillary ligands bonded to the "(C,N)Pd" fragment. (c) 2005 Elsevier B.V. All rights reserved.

引用

页码：1373 / 1390

页数：18

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