Microstructure and high-temperature oxidation resistance of Ti-Al-Nb coatings on a Ti-6Al-4V alloy fabricated by laser surface alloying

被引:69
作者
Dai, Jingjie [1 ,2 ]
Li, Shouying [1 ,2 ]
Zhang, Hongxia [1 ,2 ]
Yu, Huijun [3 ]
Chen, Chuanzhong [4 ]
Li, Yang [5 ]
机构
[1] Qingdao Binhai Univ, Univ Shandong, Key Lab New Metall Funct Mat & Adv Surface Engn, Qingdao 266555, Shandong, Peoples R China
[2] Qingdao Binhai Univ, Sch Mech & Elect Engn, Qingdao 266555, Shandong, Peoples R China
[3] Shandong Univ, Sch Mech Engn, Minist Educ, Key Lab High Efficiency & Clean Mech Manufacture, Jinan 250061, Shandong, Peoples R China
[4] Shandong Univ, Sch Mat Sci & Engn, Minist Educ, Key Lab Liquid Solid Struct Evolut & Proc Mat, Jinan 250061, Shandong, Peoples R China
[5] Jinan Worldwide Autoaccessory Ltd, Jinan 250300, Shandong, Peoples R China
关键词
Titanium alloy; Laser surface alloying; Ti-Al-xNb coating; High-temperature oxidation resistance; TITANIUM ALUMINIDES; BEHAVIOR;
D O I
10.1016/j.surfcoat.2018.03.060
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
In this study, Ti-Al-xNb coatings were deposited on a Ti-6Al-4V alloy by laser surface alloying in order to investigate their oxidation resistance. A Ti-Al coating was fabricated for comparison. It was found that the Ti-Al and Ti-Al-xNb coatings were composed of TiAl and Ti3Al phases. Nb addition reduced the cracking tendency of the Ti-Al-xNb coatings. The Ti-Al and Ti-Al-xNb coatings exhibited good high-temperature oxidation resistance at 800 degrees C. In comparison, Ti-Al-xNb (x = 10, 20, 30 and 40) coatings had better high-temperature oxidation resistance and Ti-Al-40Nb coating had the best high-temperature oxidation resistance. The mechanism of Nb that improves the high-temperature oxidation resistance of Ti-Al-xNb coatings includes preventing the internal diffusion of oxygen, inhibiting the formation of TiO2, promoting the formation of Al2O3 and increasing the adhesion of the oxide scales.
引用
收藏
页码:479 / 488
页数:10
相关论文
共 30 条
[1]   Oxidation behavior of in-situ Al2O3/TiAl composites at 900°C in static air [J].
Ai, Tao-tao ;
Wang, Fen ;
Feng, Xiao-ming .
INTERNATIONAL JOURNAL OF MINERALS METALLURGY AND MATERIALS, 2009, 16 (03) :339-344
[2]   Investigation of the ordering and atomic site occupancies of Nb-doped TiAl/Ti3Al intermetallics [J].
Al-Kassab, Tala'at ;
Yuan, Yong ;
Kluthe, Christian ;
Boll, Torben ;
Liu, Zhi-Guo .
SURFACE AND INTERFACE ANALYSIS, 2007, 39 (2-3) :257-261
[3]   Effect of niobium alloying level on the oxidation behavior of titanium aluminides at 850°C [J].
Banu, Alexandra ;
Marcu, Maria ;
Petrescu, Simona ;
Ionescu, Nicolae ;
Paraschiv, Alexandru .
INTERNATIONAL JOURNAL OF MINERALS METALLURGY AND MATERIALS, 2016, 23 (12) :1452-1457
[4]   Oxidation behavior of niobized TiAl by plasma surface alloying [J].
Chen, Dongdong ;
Tian, Wenhuai ;
Wang, Jian ;
Liu, Xiaoping .
JOURNAL OF UNIVERSITY OF SCIENCE AND TECHNOLOGY BEIJING, 2008, 15 (05) :590-593
[5]   Micro segregation in high Nb containing TiAl alloy ingots beyond laboratory scale [J].
Chen, G. L. ;
Xu, X. J. ;
Teng, Z. K. ;
Wang, Y. L. ;
Lin, J. P. .
INTERMETALLICS, 2007, 15 (5-6) :625-631
[6]   Microstructure and properties of Ti-Al coating and Ti-Al-Si system coatings on Ti-6Al-4V fabricated by laser surface alloying [J].
Dai, Jingjie ;
Zhang, Fengyun ;
Wang, Amin ;
Yu, Huijun ;
Chen, Chuanzhong .
SURFACE & COATINGS TECHNOLOGY, 2017, 309 :805-813
[7]   EFFECT OF SURFACE ALUMINIZING ON LONG-TERM HIGH-TEMPERATURE THERMAL STABILITY OF TC4 TITANIUM ALLOY [J].
Dai, Jingjie ;
Zhu, Jiyun ;
Zhuang, Lei ;
Li, Shouying .
SURFACE REVIEW AND LETTERS, 2016, 23 (02)
[8]   High temperature air oxidation resistance of TiAlCr-Y coated Ti45Al8Nb between 750 degrees C - 950 degrees C [J].
Dudziak, Tomasz ;
Datta, Prasanta ;
Du, Hailiang ;
Ross, Ian Mark .
OPEN ENGINEERING, 2013, 3 (04) :722-731
[9]   Structural Stability from Crystallographic Shear in TiO2-Nb2O5 Phases: Cation Ordering and Lithiation Behavior of TiNb24O62 [J].
Griffith, Kent J. ;
Senyshyn, Anatoliy ;
Grey, Clare P. .
INORGANIC CHEMISTRY, 2017, 56 (07) :4002-4010
[10]   Oxidation behavior and microstructural evolution of hot-dipped aluminum coating on Ti-6Al-4V alloy at 800 °C [J].
Jeng, Shiang-Cheng .
SURFACE & COATINGS TECHNOLOGY, 2013, 235 :867-874