Self-propagating association of zwitterionic polymers initiated by ionene polymers

被引：0
|
作者：
Okawa, K [1 ]
Gong, PP [1 ]
Osada, Y [1 ]
机构：
[1] Hokkaido Univ, Div Biol Sci, Grad Sch Sci, Sapporo, Hokkaido 0600810, Japan
来源：
MACROMOLECULAR RAPID COMMUNICATIONS | 2002年 / 23卷 / 07期
关键词：
association; electrostatic interaction; ionene polymers; polyelectrolytes; polyion complex; zwitterions;
D O I：
10.1002/1521-3927(20020401)23:7<423::AID-MARC423>3.0.CO;2-F
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A self-propagating association of zwitterionic polymers is observed when a small amount of x,y-ionene bromide (x=3 or 6; y=3, 4, 6, 10 or 12) polymer is added to aqueous solution of zwitterionic polymer, poly[3-dimethyl(methacryloyloxyethyl)ammoniumpropanesulfonate] (PDMAPS), to give large amount of PDMAPS precipitate. The self-propagating association initiated by ionene polymers is explained in terms of the electrostatic interaction between the ionene polymers and the zwitterionic polymers whereupon the geometry of the charges on the polymer chains plays an important role.
引用
收藏
页码：423 / 425
页数：3
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