Facile and green fabrication of cellulosed based aerogels for lampblack filtration from waste newspaper

被引:52
作者
Fan, Peidong [1 ]
Yuan, Yali [1 ]
Ren, Junkai [1 ]
Yuan, Bin [1 ,2 ]
He, Qian [1 ]
Xia, Guangmei [2 ]
Chen, Fengxia [1 ]
Song, Rui [1 ]
机构
[1] Univ Chinese Acad Sci, Coll Chem & Chem Engn, Beijing 100049, Peoples R China
[2] Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Key Lab Engn Plast, Beijing 100190, Peoples R China
基金
美国国家科学基金会;
关键词
Waste newspaper; Cellulose; Aerogel; Cellulose based aerogel; INTERNATIONAL STANDARDS; FILTERS; PRETREATMENT; SIZE;
D O I
10.1016/j.carbpol.2017.01.015
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
In this study, the lightweight, hydrophobic and porous cellulose-based aerogels (CAGs) were synthesized through a freeze-drying process using waste newspaper as the only raw material. After crosslinking with glutaraldehyde and treatment with trimethylchlorosilane (TMCS) using a simple thermal chemical vapor deposition process, the resulting CAGs became hydrophobic and oleophilic. Furthermore, the as-prepared CAGs exhibited a low density (17.4-28.7 mg cm(-3)) and mesoporous inner-structure. All these properties attributed the novel aerogel not only with a good adsorption capability of oils and organic solvents, including kerosene, nitrobenzene, and chloroform, but also an excellent filtration capacity of lampblack. (C) 2017 Elsevier Ltd. All rights reserved.
引用
收藏
页码:108 / 114
页数:7
相关论文
共 34 条
[1]   Structure and Properties of Novel Regenerated Cellulose Films Prepared from Cornhusk Cellulose in Room Temperature Ionic Liquids [J].
Cao, Yan ;
Li, Huiquan ;
Zhang, Yi ;
Zhang, Jun ;
He, Jiasong .
JOURNAL OF APPLIED POLYMER SCIENCE, 2010, 116 (01) :547-554
[2]   Cellulose nanowhisker foams by freeze casting [J].
Dash, Rajalaxmi ;
Li, Yang ;
Ragauskas, Arthur J. .
CARBOHYDRATE POLYMERS, 2012, 88 (02) :789-792
[3]   Toxicology of nanoparticles [J].
Elsaesser, Andreas ;
Howard, C. Vyvyan .
ADVANCED DRUG DELIVERY REVIEWS, 2012, 64 (02) :129-137
[4]   FTIR ANALYSIS OF HYDROGEN-BONDING IN AMORPHOUS LINEAR AROMATIC POLYURETHANES .1. INFLUENCE OF TEMPERATURE [J].
WANG, FC ;
FEVE, M ;
LAM, TM ;
PASCAULT, JP .
JOURNAL OF POLYMER SCIENCE PART B-POLYMER PHYSICS, 1994, 32 (08) :1305-1313
[5]   Gas-phase esterification of cellulose nanocrystal aerogels for colloidal dispersion in apolar solvents [J].
Fumagalli, Matthieu ;
Sanchez, Francisco ;
Boisseau, Sonia Molina ;
Heux, Laurent .
SOFT MATTER, 2013, 9 (47) :11309-11317
[6]   Green and facile fabrication of carbon aerogels from cellulose-based waste newspaper for solving organic pollution [J].
Han, Shenjie ;
Sun, Qingfeng ;
Zheng, Huanhuan ;
Li, Jingpeng ;
Jin, Chunde .
CARBOHYDRATE POLYMERS, 2016, 136 :95-100
[7]   Cellulose nanowhisker aerogels [J].
Heath, Lindy ;
Thielemans, Wim .
GREEN CHEMISTRY, 2010, 12 (08) :1448-1453
[8]   The use of FT-IR microspectroscopic mapping to study the effects of enzymatic retting of flax (Linum usitatissimum L) stems [J].
Himmelsbach, DS ;
Khalili, S ;
Akin, DE .
JOURNAL OF THE SCIENCE OF FOOD AND AGRICULTURE, 2002, 82 (07) :685-696
[9]  
Hinds W.C., 2012, Aerosol technology: properties, behavior, and measurement of airborne particles
[10]  
Jiao K. Y., 2015, J NANOPART RES, V17, P15