Visible-light-mediated guest trapping in a photosensitizing porous coordination network: metal-free C-C bond-forming modification of metal-organic frameworks for aqueous-phase herbicide adsorption

被引：19
作者：
Yang, Yong [1 ]
Che, Jinxin [2 ]
Wang, Biao [1 ]
Wu, Yizhe [2 ]
Chen, Binhui [2 ]
Gao, Liang [3 ]
Dong, Xiaowu [2 ]
Zhao, Jinhao [1 ]
机构：
[1] Zhejiang Univ, Inst Pesticide & Environm Toxicol, Minist Agr, Key Lab Mol Biol Crop Pathogens & Insects, Hangzhou 310058, Zhejiang, Peoples R China
[2] Zhejiang Univ, ZJU ENS Joint Lab Med Chem, Hangzhou Inst Innovat Med, Coll Pharmaceut Sci, Hangzhou 310058, Zhejiang, Peoples R China
[3] Guangdong Univ Technol, Sch Chem Engn & Light Ind, Guangzhou 510006, Guangdong, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 37期
基金：
中国国家自然科学基金;
关键词：
FUNCTIONALIZATION; REMOVAL; MOF;
D O I：
10.1039/c9cc01371g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A series of furan/thiophene-derived Cr-MIL-101s were obtained via visible-light-mediated C-C bond-forming catalysis within photosensitizing porous materials. The guest trapping process was achieved under very mild and metal-free conditions, affording newly functionalized MOFs with more - stacking, hydrogen bonding properties and excellent adsorption capacity in removing herbicides from aquatic environments.
引用
收藏
页码：5383 / 5386
页数：4
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