Transient femtosecond spectroscopy in α-sexithiophene single crystals

被引:15
作者
Klein, G [1 ]
机构
[1] Inst Phys & Chim Mat Strasbourg, Opt Nonlineaire & Optoelect Grp, F-67037 Strasbourg, France
关键词
D O I
10.1016/S0009-2614(00)00199-8
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The relaxation processes of excited states in alpha-sexithiophene single crystals have been investigated by femtosecond transient spectroscopy experiments. A vibrational relaxation has been observed during the first 500 fs, leading to the bottom of the lowest Davydov exciton band. Excitons evolve slowly on a subnanosecond scale by bimolecular annihilations to the ground state and by intersystem crossing to triplet states. There is no evidence for the creation of ionized 6T(+) states. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:65 / 69
页数:5
相关论文
共 50 条
[31]   High pressure study of the intramolecular vibrational modes in sexithiophene single crystals [J].
Loi, MA ;
Cai, Q ;
Chandrasekhar, HR ;
Chandrasekhar, M ;
Graupner, W ;
Bongiovanni, G ;
Mura, A ;
Botta, C ;
Garnier, F .
SYNTHETIC METALS, 2001, 116 (1-3) :321-326
[32]   Excitation dynamics in α-sexithiophene single crystals and UHV-grown films [J].
Hopmeier, M ;
Marks, RN ;
Michel, R ;
Muccini, M ;
Murgia, M ;
Zamboni, R ;
Taliani, C ;
Horowitz, G ;
Garnier, F ;
Oestreich, M ;
Mahrt, RF .
JOURNAL OF LUMINESCENCE, 1998, 76-7 :416-419
[33]   Excitation dynamics in α-sexithiophene single crystals and UHV-grown films [J].
Philipps-Universitaet Marburg, Marburg, Germany .
J Lumin, (416-419)
[34]   Relaxation Dynamics of Photoexcited Excitons in Rubrene Single Crystals Using Femtosecond Absorption Spectroscopy [J].
Tao, S. ;
Ohtani, N. ;
Uchida, R. ;
Miyamoto, T. ;
Matsui, Y. ;
Yada, H. ;
Uemura, H. ;
Matsuzaki, H. ;
Uemura, T. ;
Takeya, J. ;
Okamoto, H. .
PHYSICAL REVIEW LETTERS, 2012, 109 (09)
[35]   Femtosecond transient spectroscopy of the photoionization of indole in water [J].
Bizjak, T ;
Bisht, PB ;
Lochbrunner, S ;
Riedle, E .
FEMTOCHEMISTRY AND FEMTOBIOLOGY: ULTRAFAST EVENTS IN MOLECULAR SCIENCE, 2004, :229-232
[36]   Radical ion pairs in sexithiophene/fullerene blends studied by transient epr spectroscopy. [J].
Pasimeni, L ;
Ruzzi, M ;
Prato, M ;
Da Ros, T ;
Barbarella, G ;
Zambianchi, M .
RECENT ADVANCES IN THE CHEMISTRY AND PHYSICS OF FULLERENES AND RELATED MATERIAL, VOL 7, 1999, 99 (12) :304-314
[37]   Confocal Raman spectroscopy of α-sexithiophene:: From bulk crystals to field-effect transistors [J].
Brillante, Aldo ;
Bilotti, Ivano ;
Albonetti, Cristiano ;
Moulin, Jean-Francois ;
Stoliar, Pablo ;
Biscarini, Fabio ;
de Leeuw, Dago M. .
ADVANCED FUNCTIONAL MATERIALS, 2007, 17 (16) :3119-3127
[38]   Growth and characterization of sexithiophene single crystals (vol 7, pg 1339, 1995) [J].
Horowitz, G ;
Bachet, B ;
Yassar, A ;
Lang, P ;
Demanze, F ;
Fave, JL ;
Garnier, F .
CHEMISTRY OF MATERIALS, 1996, 8 (04) :975-975
[39]   Disorder influenced optical properties of α-sexithiophene single crystals and thin evaporated films [J].
Marks, RN ;
Muccini, M ;
Lunedi, E ;
Michel, RH ;
Murgia, M ;
Zamboni, R ;
Taliani, C ;
Horowitz, G ;
Garnier, F ;
Hopmeier, M ;
Oestreich, M ;
Mahrt, RF .
CHEMICAL PHYSICS, 1998, 227 (1-2) :49-56
[40]   FEMTOSECOND COHERENT TRANSIENT SPECTROSCOPY OF CO ON CU[111] [J].
OWRUTSKY, JC ;
CULVER, JP ;
LI, M ;
KIM, YR ;
SARISKY, MJ ;
YEGANEH, MS ;
YODH, AG ;
HOCHSTRASSER, RM .
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1992, 204 :205-PHYS