Electrochromic devices with polymer electrolytes functionalized by SiO2 and In2O3:Sn nanoparticles: Rapid coloring/bleaching dynamics and strong near-infrared absorption

被引:25
作者
Pehlivan, Ilknur Bayrak [1 ]
Marsal, Roser [2 ]
Pehlivan, Esat [2 ]
Runnerstrom, Evan L. [3 ,4 ]
Milliron, Delia J. [3 ]
Granqvist, Claes G. [1 ]
Niklasson, Gunnar A. [1 ]
机构
[1] Uppsala Univ, Angstrom Lab, Dept Engn Sci, SE-75121 Uppsala, Sweden
[2] ChromoGenics AB, SE-75323 Uppsala, Sweden
[3] Univ Calif Berkeley, Lawrence Berkeley Natl Lab, Mol Foundry, Berkeley, CA 94720 USA
[4] Univ Calif Berkeley, Dept Mat Sci & Engn, Berkeley, CA 94720 USA
关键词
Smart windows; Polymer electrolytes; Nanoparticles; Coloring/bleaching dynamics; Near-infrared absorption; TUNGSTEN-OXIDE; ION CONDUCTION; SMART WINDOWS; NICKEL-OXIDE; THIN-FILMS;
D O I
10.1016/j.solmat.2013.06.010
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
We studied the optical properties and coloring/bleaching dynamics of electrochromic devices based on tungsten oxide and nickel oxide and incorporating polymer electrolytes functionalized by adding about one percent of nanoparticles of SiO2 (fumed silica) or In2O3:Sn. SiO2 improved the coloring/bleaching dynamics and In2O3:Sn quenched the near-infrared transmittance. Both of these effects can be important in electrochromic smart windows, and our results point at the advantage of a polymer laminated construction over a monolithic one. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码:241 / 247
页数:7
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