Copper-Catalyzed Methyl Esterification Reactions via C-C Bond Cleavage

被引：102

作者：

Zhu, Yan ^{[1
]}

Yan, Hong ^{[1
]}

Lu, Linhua ^{[1
]}

Liu, Defu ^{[1
]}

Ron, Guangwei ^{[1
]}

Mao, Jincheng ^{[1
]}

机构：

[1] Soochow Univ, Key Lab Organ Synth Jiangsu Prov, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2013年 / 78卷 / 19期

关键词：

BENZYLIC ALCOHOLS; OXIDATIVE ESTERIFICATION; COUPLING REACTIONS; ARYL HALIDES; CARBOXYLIC-ACIDS; ALPHA-DDB; BETA-DDB; ALDEHYDES; ESTERS; ACTIVATION;

D O I：

10.1021/jo4016387

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The highly effective synthesis of methyl esters from benzylic alcohols, aldehydes, or acids via copper-catalyzed C-C cleavage from tert-butyl hydroperoxide is reported in this paper for the first time. Our protocol is easily accessible and practical, making it a possible supplement for the traditional way.

引用

页码：9898 / 9905

页数：8

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