Palladium-Catalyzed Desulfitative Cross-Coupling Reaction of Sodium Sulfinates with Propargylic Carbonates

被引：7
|
作者：
Qin, Anni [1 ]
Zhu, Guirong [1 ]
Chen, Qin [1 ]
Qian, Hui [1 ]
Ma, Shengming [1 ,2 ]
机构：
[1] Fudan Univ, Res Ctr Mol Recognit & Synth, Dept Chem, 220 Handan Lu, Shanghai 200433, Peoples R China
[2] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, 345 Lingling Lu, Shanghai 200032, Peoples R China
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2019年 / 361卷 / 20期
基金：
中国国家自然科学基金;
关键词：
Desulfitative; Cross-Coupling; Sodium Sulfinates; Allenes; ARENESULFINIC ACID SALTS; DIRECT ESI-MS; ARYL KETONES; PALLADIUM(0)-CATALYZED CONVERSION; C-O; ALLENES; ARYLATION; ALCOHOLS; CHEMISTRY; REAGENTS;
D O I：
10.1002/adsc.201900698
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Desulfitative cross-coupling of propargylic carbonates with sodium sulfinates has been observed. The reaction exhibited good functional group compatibility affording allenes as a single product. Potential anticancer activities of these allene products were also studied.
引用
收藏
页码：4656 / 4660
页数：5
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