C2-symmetric chiral bis(oxazoline) ligands in asymmetric catalysis

被引:739
作者
Desimoni, Giovanni
Faita, Giuseppe
Jorgensen, Karl Anker
机构
[1] Univ Pavia, Dept Organ Chem, I-27100 Pavia, Italy
[2] Aarhus Univ, Dept Chem, Ctr Catalysis, Danish Natl Res Fdn, DK-8000 Aarhus C, Denmark
关键词
D O I
10.1021/cr0505324
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
This review covers the history of box ligands since their introduction in 1991 by Corey and Evans to the spring of 2005. Box ligands are synthesized by the construction of the oxazolidine rings, the substitution of two hydrogen atoms with two identical groups on the spacer of a preformed box and the manipulations of either the chiral groups on the oxazoline rings (C1) or the groups on the spacer (C2). The capacity of the box's to behave as chiral ligands in the formation first of complexes with inorganic salts and then of reaction complexes makes these heterocyclic derivatives a precious source of catalysts whose versatility has been demonstrated in a number of catalytic asymmetric syntheses.
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页码:3561 / 3651
页数:91
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