Ag(I)-Mediated Oxidative Radical TriFLuoromethylthiolation of Alkenes

被引：6
|
作者：
Zheng, Changge [1 ,2 ]
Liu, Yang [1 ]
Hong, Jianquan [1 ]
Huang, Shuai [1 ]
Zhang, Wei [2 ]
Yang, Yupeng [1 ]
Fang, Ge [2 ]
机构：
[1] Jiangnan Univ, Sch Chem & Mat Engn, Minist Educ, Key Lab Synthet & Biol Colloids, Wuxi 214122, Jiangsu, Peoples R China
[2] Xinjiang Agr Univ, Sch Chem Engn, Urumqi 830052, Xinjiang Uygur, Peoples R China
来源：
SYNLETT | 2019年 / 30卷 / 11期
基金：
中国国家自然科学基金;
关键词：
triFLuoromethylthiolation; alkenes; AgSCF; (3); alpha-SCF; -substituted ketone; radical pathway; HYPERVALENT IODINE REAGENT; CATALYZED SYNTHESIS; ELECTROPHILIC TRIFLUOROMETHYLTHIOLATION; DECARBOXYLATIVE TRIFLUOROMETHYLTHIOLATION; SILVER(I) TRIFLUOROMETHANETHIOLATE; FLUOROALKYLATION REACTIONS; COPPER; KETONES; ETHERS; HYDROTRIFLUOROMETHYLTHIOLATION;
D O I：
10.1055/s-0037-1611546
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A simple, mild, and efficient method for an oxidative radical triFLuoromethylthiolation of alkenes through AgSCF (3) /K (2) S (2) O (8) system has been developed. This reaction provides a straightforward way to synthesize a variety of useful alpha-SCF (3) -substituted ketone compounds from a wide range of alkenes in moderate to good yields.
引用
收藏
页码：1324 / 1328
页数：5
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