Tailoring Crystal Facets of Metal-Organic Layers to Enhance Photocatalytic Activity for CO2 Reduction

被引：231

作者：

Yang, Wei ^{[1
]}

Wang, Hong-Juan ^{[1
]}

Liu, Rui-Rui ^{[1
]}

Wang, Jia-Wei ^{[2
]}

Zhang, Chao ^{[1
]}

Li, Chao ^{[1
]}

Zhong, Di-Chang ^{[1
]}

Lu, Tong-Bu ^{[1
]}

机构：

[1] Tianjin Univ Technol, Sch Mat Sci & Engn, Inst New Energy Mat & Low Carbon Technol, Tianjin 300384, Peoples R China

[2] Sun Yat Sen Univ, Sch Chem, KLGHEI Environm & Energy Chem, Guangzhou 510275, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2021年 / 60卷 / 01期

基金：

中国国家自然科学基金;

关键词：

crystal engineering; crystal facet tuning; heterogeneous catalysis; metal– organic layers; photocatalytic CO2 reduction; ATOMICALLY THIN; FRAMEWORKS;

D O I：

10.1002/anie.202011068

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

It is common that different crystal facets in metal and metal oxide nanocrystals display different catalytic performances, whereas such phenomena have been rarely documented in metal-organic frameworks (MOFs). Herein, we demonstrate for the first time that a nickel metal-organic layer (MOL) exposing rich (100) crystal facets (Ni-MOL-100) shows a much higher photocatalytic CO2-to-CO activity than the one exposing rich (010) crystal facets (Ni-MOL-010) and its bulky counterpart (bulky Ni-MOF), with a catalytic activity up to 2.5 and 4.6 times more active than Ni-MOL-010 and bulky Ni-MOF, respectively. Theoretical studies reveal that the two coordinatively unsaturated Ni-II ions with a close distance of 3.50 angstrom on the surface of Ni-MOL-100 enables synergistic catalysis, leading to more favorable energetics in CO2 reduction than that of Ni-MOL-010.

引用

页码：409 / 414

页数：6

共 47 条

[1] Metal-organic frameworks for photocatalytic CO2 reduction under visible radiation: A review of strategies and applications [J].

Alkhatib, Ismail Issa ;

Garlisi, Corrado ;

Pagliaro, Mario ;

Al-Ali, Khalid ;

Palmisano, Giovanni .

CATALYSIS TODAY, 2020, 340 :209-224

[2] Optimal sizing and location based on economic parameters for an off-grid application of a hybrid system with photovoltaic, battery and diesel technology [J].

Cai, Wei ;

Li, Xing ;

Maleki, Akbar ;

Pourfayaz, Fathollah ;

Rosen, Marc A. ;

Nazari, Mohammad Alhuyi ;

Dieu Tien Bui .

ENERGY, 2020, 201

[3] Ab initio crystal structure of nickel(II) hydroxy-terephthalate by synchrotron powder diffraction and magnetic study [J].

Carton, Anne ;

Mesbah, Adel ;

Mazet, Thomas ;

Porcher, Florence ;

Francois, Michel .

SOLID STATE SCIENCES, 2007, 9 (06) :465-471

[4] Highly efficient and selective photocatalytic CO2 to CO conversion in aqueous solution [J].

Chai, Xiaomin ;

Huang, Hai-Hua ;

Liu, Huiping ;

Ke, Zhuofeng ;

Yong, Wen-Wen ;

Zhang, Ming-Tian ;

Cheng, Yuan-Sheng ;

Wei, Xian-Wen ;

Zhang, Liyan ;

Yuan, Guozan .

CHEMICAL COMMUNICATIONS, 2020, 56 (27) :3851-3854

[5] Metal-organic frameworks (MOFs) for photocatalytic CO2 reduction [J].

Chen, Yi ;

Wang, Dengke ;

Deng, Xiaoyu ;

Li, Zhaohui .

CATALYSIS SCIENCE & TECHNOLOGY, 2017, 7 (21) :4893-4904

[6] Generation of coherent spin-wave modes in yttrium iron garnet microdiscs by spin-orbit torque [J].

Collet, M. ;

de Milly, X. ;

Kelly, O. d'Allivy ;

Naletov, V. V. ;

Bernard, R. ;

Bortolotti, P. ;

Ben Youssef, J. ;

Demidov, V. E. ;

Demokritov, S. O. ;

Prieto, J. L. ;

Munoz, M. ;

Cros, V. ;

Anane, A. ;

de Loubens, G. ;

Klein, O. .

NATURE COMMUNICATIONS, 2016, 7

[7] The role of reticular chemistry in the design of CO2 reduction catalysts [J].

Diercks, Christian S. ;

Liu, Yuzhong ;

Cordova, Kyle E. ;

Yaghi, Omar M. .

NATURE MATERIALS, 2018, 17 (04) :301-307

[8] Co3O4 Hexagonal Platelets with Controllable Facets Enabling Highly Efficient Visible-Light Photocatalytic Reduction of CO2 [J].

Gao, Chao ;

Meng, Qiangqiang ;

Zhao, Kun ;

Yin, Huajie ;

Wang, Dawei ;

Guo, Jun ;

Zhao, Shenlong ;

Chang, Lin ;

He, Meng ;

Li, Qunxiang ;

Zhao, Huijun ;

Huang, Xingjiu ;

Gao, Yan ;

Tang, Zhiyong .

ADVANCED MATERIALS, 2016, 28 (30) :6485-+

[9]

Guntern Y. T., 2019, ANGEW CHEM, V131

[10] Nanocrystal/Metal-Organic Framework Hybrids as Electrocatalytic Platforms for CO2 Conversion [J].

Guntern, Yannick T. ;

Pankhurst, James R. ;

Vavra, Jan ;

Mensi, Mounir ;

Mantella, Valeria ;

Schouwink, Pascal ;

Buonsanti, Raffaella .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2019, 58 (36) :12632-12639

← 1 2 3 4 5 →