RETRACTED: Introduction of a trinuclear manganese(iii) catalyst on the surface of magnetic cellulose as an eco-benign, efficient and reusable novel heterogeneous catalyst for the multi-component synthesis of new derivatives of xanthene (Retracted Article)

被引:38
作者
Kargar, Pouya Ghamari [1 ]
Bagherzade, Ghodsieh [1 ]
Eshghi, Hossein [2 ]
机构
[1] Univ Birjand, Fac Sci, Dept Chem, Birjand 97175615, Iran
[2] Ferdowsi Univ Mashhad, Fac Sci, Dept Chem, Mashhad, Razavi Khorasan, Iran
关键词
ONE-POT SYNTHESIS; RECOVERABLE NANO-CATALYST; FACILE SYNTHESIS; IONIC LIQUID; RECYCLABLE CATALYST; NATURAL PHOSPHATE; HIGHLY EFFICIENT; GREEN CHEMISTRY; SULFONIC-ACID; NANOPARTICLES;
D O I
10.1039/d0ra09420j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this work, the new trinuclear manganese catalyst defined as Fe3O4@NFC@NNSM-Mn(iii) was successfully manufactured and fully characterized by different techniques, including FT-IR, XRD, TEM, SEM, EDX, VSM, and ICP analysis. There have been reports of the use of magnetic catalysts for the synthesis of xanthine derivatives. The critical potential interest in the present method include short reaction time, high yields, recyclability of the catalyst, easy workup, and the ability to sustain a variety of functional groups, which give economical as well as ecological rewards. Also, the synthesized catalyst was used as a recyclable trinuclear catalyst in alcohol oxidation reactions at 40 degrees C. The magnetic catalyst activity of Fe3O4@NFC@NNSM-Mn(iii) could be attributed to the synergistic effects of the catalyst Fe3O4@NFC@NNS-Mn(iii) with melamine. Employing a sustainable and safe low temperature, using an eco-friendly solvent, no need to use any additive, and long-term stability and magnetic recyclability of the catalyst for at least six successive runs are the advantages of the current protocol towards green chemistry. This protocol is a benign, environmentally friendly method for heterocycle synthesis.
引用
收藏
页码:4339 / 4355
页数:17
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