pH Dependent Synthesis of Two Manganese Compounds based on 5-(2-Pyrimidyl)tetrazole-1-acetic Acid

被引：8
作者：
Li, Xiu Yun [1 ]
Zhang, Ping [1 ]
Tian, He [1 ]
Zhu, Da Liang [1 ]
Zhang, Fei Fei [1 ]
Li, Qiao Yun [1 ]
Yang, Gao Wen [1 ]
Wei, Bo [1 ]
Zou, Jian Hua [1 ]
机构：
[1] Changshu Inst Technol, Dept Chem & Mat Engn, Jiangsu Lab Adv Funct Mat, Changshu 215500, Peoples R China
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2015年 / 641卷 / 11期
关键词：
pH value; Manganese; 5-(2-Pyrimidyl)tetrazole-1-acetic acid; Crystal structure; Luminescence; CRYSTAL-STRUCTURE; COORDINATION; HPZTZA;
D O I：
10.1002/zaac.201500134
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reactions of Hpymtza [Hpymtza = 5-(2-pyrimidyl)tetrazole-1-acetic acid] with MnCl2 center dot 4H(2)O under different pH conditions, afforded the complexes [Mn(pymtza)(2)(H2O)(4)] (1) and [Mn-2(pymtza)(2)Cl-2(EtOH)]center dot H2O (2). The compounds were structurally characterized by elemental analysis, IR spectroscopy and single-crystal X-ray diffraction. Compound 1 shows a mononuclear structure, whereas complex 2 has a 1D chain structure. In compound 1, the pymtza ligand only acts in a monodentate manner to coordinate to one central Mn-II atom by one carboxylate atom, In 2, pymtza acts as tetradentate ligand to connect three MnII ions. Compounds 1 and 2 display 3D networks by hydrogen bonding interactions. Furthermore, the luminescence properties of Hpymtza as well as compounds 1 and 2 were investigated at room temperature in the solid state.
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页码：1948 / 1952
页数：5
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