The liquid-phase oxidation of olefins by molecular oxygen in the presence of metal borides and MoO3

被引：9

作者：

Trach, Yu.

Schulze, B.

Makota, O.

Bulgakova, L.

机构：

[1] Lviv Polytech Natl Univ, UA-79013 Lvov, Ukraine

[2] Univ Leipzig, Inst Organ Chem, D-04103 Leipzig, Germany

来源：

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2006年 / 258卷 / 1-2期

关键词：

oxidation; epoxidation; olefine; molecular oxygen; hydroperoxide; catalysts;

D O I：

10.1016/j.molcata.2006.05.069

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The initial stages of the liquid-phase oxidation of 1-octene and cyclooctene by molecular oxygen in the presence of transition metal borides and MoO3 are investigated. The investigated compounds influence the oxidation process only in the presence of hydroperoxide in the reaction system. The most active in this process is vanadium diboride. The molybdenum compounds activate the oxidation process of 1-octene and inhibit the oxidation of cyclooctene. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：292 / 294

页数：3

共 17 条

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[2]

Beller M., 2004, TRANSITION METALS OR, DOI 10.1002/9783527619405

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