Effect of sintering aid CuO-MnO2 on dielectric properties of 0.5Ba(Mg1/3Nb2/3)O3-0.5Ba(Ni1/3Nb2/3)O3 ceramics

被引:4
作者
Tian Zhongqing [1 ]
Zhang Chunyan [1 ]
Wang Hao [2 ]
Huang Weijiu [1 ]
Lin Lin [1 ]
机构
[1] Chongqing Inst Technol, Sch Mat Sci & Engn, Chongqing 400050, Peoples R China
[2] Wuhan Univ Technol, Sch Mat Sci & Engn, Wuhan 430070, Peoples R China
来源
JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY-MATERIALS SCIENCE EDITION | 2009年 / 24卷 / 01期
关键词
ceramics; oxides; X-ray diffraction; dielectric properties; BA(MG1/3TA2/3)O-3 CERAMICS; MICROWAVE FREQUENCY; MICROSTRUCTURE; BA(ZN1/3TA2/3)O-3; RESONATOR; ADDITIVES; SYSTEM; PHASE; CUO;
D O I
10.1007/s11595-009-1123-7
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Microstructures and microwave dielectric properties of 0.5Ba(Mg1/3Nb2/3)O-3-0.5Ba(Ni1/3Nb2/3)O-3 ceramics with x wt% CuO-x wt% MnO2 additions (x=0.25-1) prepared by conventional solid-state route were investigated. It is found that low level-doping of CuO-MnO2 can significantly improve the density of the specimens and their microwave dielectric properties. The relative density of 0.5Ba(Mg1/3Nb2/3)O-3-0.5Ba(Ni1/3Nb2/3)O-3 ceramics can be increased by 95% sintering at 1 330 A degrees C due to the liquid phase effect. The second phase is not observed in ceramics with CuO-MnO2 addition. The parameter epsilon (r) increases with increasing sintering temperature, and Q (f) is effectively promoted by CuO-MnO2 addition. Higher CuO-MnO2 content would make tau(f) value more positive. Meanwhile, epsilon (r) value of 30.5, Q (f) value of 63 200 GHz and tau (f) value of 0.5 ppm/A degrees C were obtained for 0.5Ba(Mg1/3Nb2/3)O-3-0.5Ba(Ni1/3Nb2/3)O-3 ceramics with 0.5 wt% CuO-0.5 wt% MnO2 addition sintered at 1 330 A degrees C for 4 h.
引用
收藏
页码:123 / 126
页数:4
相关论文
共 22 条
[1]   Influence of glass additives on the microwave dielectric properties of Ca5Nb2TiO12 ceramics [J].
Bijumon, PV ;
Sebastian, MT .
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2005, 123 (01) :31-40
[2]   TEMPERATURE DEPENDENCE OF DIELECTRIC CONSTANTS OF CUBIC IONIC COMPOUNDS [J].
BOSMAN, AJ ;
HAVINGA, EE .
PHYSICAL REVIEW, 1963, 129 (04) :1593-&
[3]   Microwave dielectric properties and microstructures of La(Mg1/2Ti1/2)O3 with CuO-doped [J].
Chen, YB ;
Huang, CL ;
Lo, CW .
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2006, 128 (1-3) :98-102
[4]   Microwave dielectric properties and low-temperature sintering of MgTiO3-SrTiO3 ceramics with B2O3 or CuO [J].
Cho, WW ;
Kakimoto, K ;
Ohsato, H .
MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2005, 121 (1-2) :48-53
[5]   Dielectric properties of copper oxide doped 0.95Ba(Zn1/3Ta2/3)O3-0.05BaZrO3 ceramics at microwave frequency [J].
Huang, CL ;
Lin, RJ ;
Tzeng, JF .
MATERIALS CHEMISTRY AND PHYSICS, 2006, 97 (2-3) :256-260
[6]   Liquid phase sintering and microwave dielectric properties of Ba(Mg1/3Ta2/3)O3 ceramics [J].
Huang, CL ;
Lin, RJ .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 2002, 41 (2A) :712-716
[7]   Dielectric properties of B2O3-doped (1-x)LaAlO3-xSrTiO3 ceramic system at microwave frequency [J].
Huang, CL ;
Chiang, KH .
MATERIALS RESEARCH BULLETIN, 2002, 37 (12) :1941-1948
[8]   Niobate-based microwave dielectrics suitable for third generation mobile phone base stations [J].
Hughes, H ;
Iddles, DM ;
Reaney, IM .
APPLIED PHYSICS LETTERS, 2001, 79 (18) :2952-2954
[9]   Effect of grain size and secondary phase on microwave dielectric properties of Ba(Mg1/3Ta2/3)O3 and Ba([Mg,Zn]1/3Ta2/3)O3 systems [J].
Ichinose, N ;
Shimada, T .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2006, 26 (10-11) :1755-1759
[10]   Low-temperature synthesis of Ba(Mg1/3Ta2/3)O-3 ceramics from Ba-Mg-Ta alkoxide precursor [J].
Katayama, S ;
Yoshinaga, I ;
Yamada, N ;
Nagai, T .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1996, 79 (08) :2059-2064