One trinuclear copper(II) complex derived from a new Schiff base ligand based on the dianion of 4-chloro-6-(hydroxymethyl)-2-((3-aminopropylimino)methyl)-phenol: Synthesis, structure, spectroscopic and magnetic properties

被引：11

作者：

Jiang, Juechao ^{[1
]}

Chu, Zhaolian ^{[1
]}

Huang, Wei ^{[1
]}

机构：

[1] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing Natl Lab Microstruct, Sch Chem & Chem Engn, Nanjing 210093, Jiangsu, Peoples R China

来源：

INORGANICA CHIMICA ACTA | 2009年 / 362卷 / 08期

基金：

中国国家自然科学基金;

关键词：

Copper(II) complex; Schiff base complex; Trinuclear complex; Crystal structure; CRYSTAL-STRUCTURES; END-ON; AZIDO; ACETATO;

D O I：

10.1016/j.ica.2008.11.018

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A linear trinuclear copper(II) complex (1), prepared from a new Schiff base ligand, namely the dianion of 4-chloro-6-(hydroxymethyl)-2-((3-aminopropylimino)methyl)-phenol, was synthesized and characterized in this paper. The X-ray structural study reveals that the geometry of the central Cu2 ion is elongated octahedral and that of the two side Cu(II) ions is distorted square pyramidal. The magnetic susceptibility measurements from 2 to 300 K reveal medium antiferromagnetic interactions between the Cu( II) ions with a J value of -64.6(1) cm(-1). (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：2933 / 2936

页数：4

共 29 条

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[2]

*BRUK AXS INC, 2000, BRUKER SMART SAINT S

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